Stokes Scattering

Stokes scattering is an inelastic light-scattering process in which the scattered photon has lower energy and a longer wavelength than the incident photon. In molecular systems, the incident light briefly drives the molecule to a virtual state, after which it emits a photon while retaining energy as vibrational or rotational excitation; the resulting red-shifted signal reflects molecular energy-level differences. Chemists use Stokes scattering in Raman spectroscopy to identify compounds, determine molecular structure, and analyze chemical composition without extensive sample preparation. Measuring the positions and intensities of Stokes bands also supports reaction monitoring, materials characterization, and studies of molecular interactions.

Stokes Scattering - Related Videos

Research

JoVE Journal - Engineering

Stimulated Stokes and Antistokes Raman Scattering in Microspherical Whispering Gallery Mode Resonators

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Cited by 1 •

2016

Efficient generation of nonlinear phenomena related to third order optical non-linear susceptibility Χ(3) interactions in triply resonant silica microspheres is presented in this paper. The interactions here reported are: Stimulated Raman Scattering (SRS), and four wave mixing processes comprising Stimulated Anti-stokes Raman Scattering (SARS).

Research

JoVE Journal - Biology
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Differential Imaging of Biological Structures with Doubly-resonant Coherent Anti-stokes Raman Scattering (CARS)

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Cited by 2 •

2010

A combination of three single wavelength short-pulsed lasers is used to generate coherent anti-Stokes Raman scattering (CARS) and doubly-resonant CARS (DR-CARS). The difference between these signals provides enhanced sensitivity for otherwise difficult to detect coherent Raman signals, enabling imaging of weak Raman scatterers.

Direct Comparison of Hyperspectral Stimulated Raman Scattering and Coherent Anti-Stokes Raman Scattering Microscopy for Chemical Imaging

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Cited by 7 •

2022

This paper directly compares the resolution, sensitivity, and imaging contrasts of stimulated Raman scattering (SRS) and coherent anti-Stokes Raman scattering (CARS) integrated into the same microscope platform. The results show that CARS has a better spatial resolution, SRS gives better contrasts and spectral resolution, and both methods have similar sensitivity.

Research

JoVE Journal - Engineering
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Coherent anti-Stokes Raman Scattering (CARS) Microscopy Visualizes Pharmaceutical Tablets During Dissolution

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Cited by 25 •

2014

Coherent anti-Stokes Raman scattering (CARS) microscopy is combined with an intrinsic flow-through dissolution setup to allow in situ and real-time visualization of the surface of pharmaceutical tablets undergoing dissolution. Using this custom-built setup, it is possible to correlate CARS videos with drug dissolution profiles recorded using inline UV absorption spectroscopy.

Education

JoVE Core - Physics

Stokes' Law

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2025

Viscous forces, like friction, are intermolecular forces that resist the relative motion of molecules over each other. When a solid body moves through a liquid, viscous forces drag it in the opposite direction. The force's magnitude depends on the solid's shape and size, as well as its speed and the liquid's coefficient of viscosity, density and temperature. The expression for the force on a solid spherical object in a fluid is called Stokes' law. Stokes' law is valid only for low Reynolds...

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