21.9
In the Carnot cycle, since all the steps are reversible, the cycle itself is reversible. A Carnot engine that operates in reverse converts work into heat. It is called a Carnot refrigerator.
Let a Carnot refrigerator operate between hot and cold reservoirs of temperatures T-h and T-c, respectively.
The relationship between the heat rejected to the hot reservoir, Q-h, the heat extracted from the cold reservoir, Q-c, and the known temperatures T-h and T-c, is the same as a Carnot engine.
Suppose it was possible to have a heat engine working between the same temperatures but having greater efficiency than a Carnot engine. Then, it could be combined with a Carnot refrigerator to show that the combined engine is equivalent to a perfect heat engine which violates the second law of thermodynamics.
It motivates the Carnot Principle, which states that no engine working between two reservoirs can have greater efficiency than a reversible engine.
The principle helps us define ideal, reversible processes as those that maximize the efficiency of a heat engine operating between two temperatures.
The Carnot engine works between two heat reservoirs of fixed temperatures. The Carnot cycle begs the following question: Is it possible to devise a he…
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