Types of Cement II

Slag cement is produced by intergrinding Portland cement clinker with granulated blast-furnace slag, a by-product of iron-making, which comprises 25 to 65 percent of the cement's weight. It is particularly suited for large structures designed to resist chloride and sulfate attack, and performs well in marine environments due to its superior sulfate resistance and lower heat of hydration.

White cement is made from chalk and china clay with fewer iron and manganese oxides, producing a distinctive white color suitable for aesthetically important applications like facades and precast panels. Colored cement is created by adding pigments to white cement. Both are more expensive due to stringent production requirements to avoid impurities and achieve color uniformity.

Expansive cements, including Types K, M, and S, combine Portland cement with an expansive agent and stabilizer. They expand during early hardening to compensate for drying shrinkage, preventing shrinkage cracking through controlled expansion due to early ettringite formation. Type K provides general shrinkage control, Type M offers sulfate resistance, and Type S is designed for high sulfate exposure.

Air-entrained Portland cement incorporates smaller quantities of air-entraining materials to form millions of microscopic air bubbles within the cement matrix. These bubbles provide spaces for water to expand into when it freezes, preventing cracking caused by freeze-thaw cycles and improving concrete durability in cold climates.

Waterproof Portland cement incorporates water-repellent substances such as calcium stearate or aluminum stearate mixed into the Portland cement clinker during grinding. These additives enhance the cement's resistance to moisture penetration, making it suitable for structures exposed to water and ensuring protection against water infiltration.

Portland blast-furnace cement has lower early strength compared to ordinary Portland cement despite similar fineness and setting times. However, it achieves comparable strength later on. Its lower heat of hydration makes it particularly suitable for mass concrete structures where reduced heat generation is beneficial.

Slag cement is ideal for marine environments and mass concrete structures due to its superior sulfate resistance and lower heat of hydration. Its ability to resist chloride and sulfate attack makes it particularly valuable for coastal structures, while its reduced heat generation prevents thermal cracking in large concrete pours.