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Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
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JoVE Journal Chemistry
Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes

DOI:
10.3791/52035-v

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09:17 min

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January 30, 2015

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, ,
1Department of Chemistry,Virginia Military Institute

Chapters

  • 00:05Title
  • 02:21Preparation of [RuII(PhTpy)(5,5′-dybpy)(MeCN)](PF6)2 Monomer Solution in Electrolyte Solution
  • 03:25Electropolymerization of [RuII(PhTpy)(5,5′-dybpy)(MeCN)](PF6)2
  • 05:58Surface Coverage Determination
  • 07:04Results: Vinyl-based Reductive Electropolymerization of Poly-pyridyl Complexes
  • 08:17Conclusion

Summary

Automatic Translation

Automatic Translation

A procedure for performing reductive electropolymerization of vinyl-containing compounds onto glassy carbon and fluorine doped tin-oxide coated electrodes is presented. Recommendations on electrochemical cell configurations and troubleshooting procedures are included. Although not explicitly described here, oxidative electropolymerization of pyrrole-containing compounds follows similar procedures to vinyl-based reductive electropolymerization.

Tags

Keywords: ElectropolymerizationSurface ModificationVinyl-containing Poly-pyridyl ComplexGlassy Carbon ElectrodeFluorine-doped Tin Oxide ElectrodeReductive PolymerizationInorganic ComplexSolar Fuels

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