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Chapters
- 00:05Title
- 01:22Synthesis of N,N,N-tris
(diphenylphosphinomethylene)amine,
N(CH2PPh2)3(N-triphosPh) - 02:44Synthesis of
[Ru(CO)2(N(CH2PPh2)3-κ3P)] - 04:25Synthesis of
[Ru(CO3)(CO)
(N(CH2PPh2)3-κ3P)] - 05:47Synthesis of [RuH2(CO)
(N(CH2PPh2)3-κ3P)] - 07:11Reaction of [RuH2(CO)
(N(CH2PPh2)3-κ3P)]
with NH4PF5 and
Levulinic Acid - 08:35Results: Characterization and Reactivity of Ruthenium
N-triphos Complexes - 10:17Conclusion
Ruthenium phosphine complexes are widely used for homogeneous catalytic reactions such as hydrogenations. The synthesis of a series of novel tridentate ruthenium complexes bearing the N-triphos ligand N(CH2PPh2)3 is reported. Additionally, the stoichiometric reaction of a dihydride Ru–N-triphos complex with levulinic acid is described.
