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Layer-by-layer Synthesis and Transfer of Freestanding Conjugated Microporous Polymer Nanomembranes

Article DOI: 10.3791/53324 • 09:09 min • December 15th, 2015
December 15th, 2015 •
1, 1, 1, 1
1Institute of Functional Interfaces, Karlsruhe Institute of Technology

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In this paper we describe the interfacial synthesis of conjugated microporous polymers (CMP) on sacrificial substrates, and the dissolution of the substrate for the preparation of freestanding CMP nanomembranes. In addition, we will describe how the fragile nanomembranes can be transferred to other substrates.

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Layer-by-layer Synthesis Transfer Freestanding Conjugated Microporous Polymer Nanomembranes CMP Large Surface Area Materials Functional Groups Thermal Stability Chemical Stability Low Densities Insoluble Nature Processing Problems Spin Coating Membrane Applications Thin Films Interfacial Synthesis Molecular Layer-by-layer (l-b-l) Synthesis Desired Thickness Composition Gradients Sacrificial Supports Freestanding Membranes Dissolution Of Support Sacrificial Coatings Nanomembranes Transfer Air-liquid Interface
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