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Chapters
- 00:05Title
- 00:47Binary CaF2 -BaF2 Electrolyte Fabrication
- 03:58Ba-Bi Alloy Electrode Fabrication and Electrical Lead Assembly
- 06:00Electrochemical Cell Assembly and Electrochemical Measurements
- 09:35Results: Electromotive Force Measurements of Ba-Bi(xBa = 0.05)|CaF2 -BaF2|Ba-Bi(xBa = 0.05, 0.10, 0.20) and Ba(s)|CaF2 -BaF2|Ba-Bi(xBa = 0.05-0.25)
- 11:23Conclusion
This protocol describes the measurement of the electromotive force of alkaline-earth elements in liquid metal alloys at high temperatures (723-1,123 K) to determine their thermodynamic properties, including activity, partial molar entropy, partial molar enthalpy, and phase transition temperatures, over a wide composition range.
