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Journal / Chemistry / [(DPEPhos) (BCP) cu] PF6: en generel og bredt…
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[(DPEPhos) (BCP) cu] PF6
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[(DPEPhos) (BCP) cu] PF6: en generel og bredt anvendelig kobber-baseret Photoredox Catalyst

Article DOI: 10.3791/59739-v • 09:12 min • May 21st, 2019
May 21st, 2019 •
1, 1, 1, 1,2, 1, 2, 1
1Laboratoire de Chimie Organique, Service de Chimie et PhysicoChimie Organiques, Université libre de Bruxelles (ULB), 2Laboratoire de Chimie Organique et Photochimie, Service de Chimie et PhysicoChimie Organiques, Université libre de Bruxelles (ULB)

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Detaljerede og generelle protokoller er præsenteret for syntesen af [(DPEPhos) (BCP) cu] PF6, en generel kobber-baseret photoredox katalysator, og for dets anvendelse i syntetisk kemi til direkte arylering af C-H obligationer i (hetero) arener og radikale af organiske halogenider.

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Kemi kobber katalyse photoredox katalyse synlige lys radikale reaktioner C-H arylering radikal cyclisering naturlige produkter cyanamider ynamides luotonin A
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