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En direkte, Regioselektiv og Atom-økonomisk syntese af 3-Aroyl-N-hydroxy-5-nitroindoler ved cyclotilsætning af 4-Nitronitrosobenzen med Alkynones
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En direkte, Regioselektiv og Atom-økonomisk syntese af 3-Aroyl-N-hydroxy-5-nitroindoler ved cyclotilsætning af 4-Nitronitrosobenzen med Alkynones

Article DOI: 10.3791/60201-v • 07:30 min • January 21st, 2020
January 21st, 2020 •
1, 1, 1, 1, 2, 1
1Dipartimento di Scienza e Alta Tecnologia, Università degli Studi dell'Insubria, 2Department of Chemistry and Biochemistry, University of Oklahoma, Stephenson Life Sciences Research Center

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3-aroyl-N-hydroxy-5-nitroindoler blev syntetiseret ved cyclotilsætning af 4-nitronitrosobenzen med en konjugeret Terminal alkynone i en et-trins termisk procedure. Præparationen af nitrosoaron og alkynones blev behørigt indberettet og henholdsvis gennem oxidations procedurer på den tilsvarende Anilin og alkynol.

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Kemi 3-aroylindoler N-hydroxyindoler nitrosoarener alkynones annulation cyclotilsætning alkynoler aniliner
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