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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)
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JoVE Journal Chemistry
Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)

DOI:
10.3791/60624-v

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08:25 min

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January 17, 2020

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, , , ,
1Department of Chemistry,Korea University, 2Department of Chemistry and BK21Plus Research Team,Chungbuk National University

Chapters

  • 00:04Title
  • 00:58(S)-KUMOF-1 Crystal Preparation
  • 03:06Zinc/(S)-KUMOF-1 Crystal Preparation
  • 03:55Titanium/(S)-KUMOF-1 Crystal Preparation
  • 04:44Carbonyl-ene Reaction
  • 06:01Results: Representative Heterogeneous Enantioselective Catalysis
  • 07:36Conclusion

Summary

Automatic Translation

Automatic Translation

Here, we present a protocol for active site validation of metal-organic framework catalysts by comparing stoichiometric and catalytic carbonyl-ene reactions to find out whether a reaction takes place on the inner or outer surface of metal-organic frameworks.

Tags

Keywords: Heterogeneous Enantioselective CatalystsChiral Metal-organic Frameworks (MOFs)Reaction Site ValidationMOF-based Catalyst CharacterizationKUMOF-1 SynthesisCopper(II)nitrateDicarboxylic Acid LigandMicrowave ReactorDEFDCMDMAZinc/KUMOF-1 Crystal PreparationDimethyl Zinc

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