Name: equilibrium calculations with mass and charge
Uploaded: 2024-04-04T10:51:15.000Z
Duration: 1 min 21 s
Channel: JoVE

K12 Standards

Tennessee Academic Standards

High School

Chemistry

Matter and Its Interactions

CHEM1.PS1.3

chemical-equilibria-systematic-approach-to-equilibrium-calculations

Chemical Equilibria: Systematic Approach to Equilibrium Calculations

في الأنظمة ذات التوازنات المتعددة ، تستخدم حسابات التوازن نهجا منهجيا يتضمن سلسلة من الخطوات للتأكد من وجود العديد من المعادلات مثل الأنواع الكيميائية.
أولا ، حدد جميع التفاعلات الكيميائية في النظام.
بعد ذلك، قم بصياغة التعبير الثابت عن الاتزان لكل تفاعل.
بعد ذلك ، قم بإنشاء معادلات توازن الكتلة التي تكشف عن مصدرين لأيونات الهيدروكسيد. تركيز أيون الهيدروكسيد من تفكك هيدروكسيد المغنيسيوم هو ضعف تركيز أيون المغنيسيوم ، وتركيز أيون الهيدروكسيد من تفكك الماء يساوي تركيز أيون الهيدرونيوم.
بعد ذلك ، قم بعمل تعبير عن توازن شحنة الأنواع الأيونية الذي يتبع مبدأ الحياد الكهربائي ، مما يعني أن تركيزات الشحنة الموجبة والسالبة في المحلول يجب أن تكون متساوية.
أخيرا ، حدد عدد المعادلات المستقلة. إذا كان الرقم يساوي أو يتجاوز عدد الأنواع الكيميائية المعنية أو المجهولة ، فإن المعادلات قابلة للحل.
غالبا ما يتم وضع افتراضات حول التركيزات النسبية للأنواع لتبسيط العمليات الحسابية.
يجب التحقق من صحة الافتراضات في الإجابة النهائية.

التوازنات الكيميائية: المنهج المنهجي لحسابات التوازن

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غالبًا ما تكون حسابات التوازن للأنظمة التي تتضمن توازنات متعددة معقدة. على سبيل المثال، لحساب قابلية ذوبان ملح قليل الذوبان في محلول مائي في وجود أيون مشترك، يجب على المرء أن يأخذ في الاعتبار جميع التوازنات في هذا المحلول. يمكن أن تكون حسابات هذه الأنظمة معقدة ومملة، لذلك غالبًا ما يكون اتباع نهج منهجي يتضمن سلسلة من الخطوات مفيدًا. العملية مفصلة أدناه.

الخطوة الأولى هي تحديد جميع التفاعلات الكيميائية المعنية، والخطوة التالية هي صياغة تعبيرات ثابت التوازن المقابلة لها. الخطوة الثالثة هي كتابة معادلات توازن الكتلة، والتي تعتمد على قانون حفظ الكتلة. تربط هذه المعادلات الكمية الإجمالية للأنواع في المحلول بأشكال مختلفة (التركيز المتوازن للأنواع) بالكمية الإجمالية لتلك الأنواع المضافة في البداية إلى المحلول (التركيز التحليلي للأنواع). قد يكون هناك أكثر من معادلة توازن الكتلة لمجموعة معينة من التوازنات. علاوة على ذلك، بالنسبة للتوازنات مع الأنواع المشحونة، يلزم وجود معادلة توازن الشحنة استنادًا إلى مبدأ الحياد الإلكتروني، والذي ينص على أن إجمالي تركيز الشحنة للأنواع المشحونة بشكل إيجابي في المحلول يجب أن يساوي تركيز الأنواع السالبة الشحنة. بالنسبة لمجموعة معينة من التوازنات، يمكن كتابة معادلة واحدة فقط لتوازن الشحنة. بعد كتابة معادلات توازن الكتلة وتوازن الشحنة، يتم حساب عدد المعادلات المستقلة التي تم الحصول عليها. إذا كان يساوي أو يتجاوز عدد المجهولين المشاركين في التوازنات، فيمكن حل المعادلات للمجاهول. بعد حل المسائل المجهولة، يجب التحقق من صحة التقديرات التقريبية لأن التقديرات التقريبية للتركيزات النسبية للأنواع غالبًا ما يتم إدخالها في معادلات توازن الكتلة أو معادلات توازن الشحنة لتبسيط الحسابات.
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في الأنظمة ذات التوازنات المتعددة ، تستخدم حسابات التوازن نهجا منهجيا يتضمن سلسلة من الخطوات للتأكد من وجود أكبر عدد ممكن من ...

Education

JoVE Core

Analytical Chemistry

الكيمياء التحليلية

Unit 1

الوحدة الأولى

Chemical Equilibria

الاتزان الكيميائي

KEY TERMS AND CONCEPTS

المصطلحات والمفاهيم الأساسية

equilibrium calculations with mass and charge

Chemical equilibrium calculations become easier when they are organized around mass balance and charge balance. This approach is useful for systems with multiple equilibria, where several reactions must be considered together. It is especially helpful when finding the solubility of a sparingly soluble salt in water with a common ion present.

The first step is to identify every chemical reaction in the system. Next, write the equilibrium constant expression for each reaction. These expressions connect the concentrations of the reacting species at equilibrium.

After that, write the mass-balance equations. A mass-balance equation uses the law of conservation of mass. It relates the total amount of a species in solution at equilibrium to the total amount originally added, which is called the analytical concentration. A single system may require more than one mass-balance equation.

If the equilibria include charged species, a charge-balance equation is also needed. This equation follows the rule of electroneutrality, which means the total positive charge in solution must equal the total negative charge. For a given set of equilibria, only one charge-balance equation can be written.

Once the equations are set up, the next step is to count the independent equations and the unknowns. If the number of independent equations equals or is greater than the number of unknowns, the system can be solved. Any approximations made along the way should be checked afterward, since mass-balance and charge-balance equations often use simplified relative concentrations.

Equilibrium Calculations with Mass and Charge

equilibrium-calculations-with-mass-and-charge

ionic strength: overview

Ionic Strength in Salt and Acid Solutions

Ionic strength describes the total electrolyte concentration in a solution. It is a quantitative measure of how many ions are present and how strongly they contribute to the solution. The concept was introduced in 1921 by Gilbert N. Lewis and Merle Randall while they were describing the activity coefficient of strong electrolytes. To calculate ionic strength, written as I or μ, both cations and anions are included. The concentration of each ion matters, but the charge number z matters even...

ionic strength: effects on chemical equilibria

ionic-strength-effects-on-chemical-equilibria

Salt Effect on Salt Solubility

Salt effect can change the solubility of a sparingly soluble salt in water. When an inert ionic compound is added, the dissolved salt may become more soluble. A common example is potassium nitrate added to a saturated calcium sulfate solution, which increases the amount of calcium sulfate that dissolves. Le Châtelier’s principle does not explain this shift well. Instead, the change is described by the effective concentration of ions in solution. Each ion is surrounded by an ionic atmosphere,...

thermodynamics: chemical potential and activity

thermodynamics-chemical-potential-and-activity

Chemical Potential in Solution Activity

Chemical potential and activity describe how a species behaves in a solution. Activity is the effective concentration of a species. It accounts for the electrolytes near that species and depends on the ionic strength of the solution. Activity is calculated as molar concentration multiplied by the activity coefficient. This makes it a more precise way to describe a species in solution than concentration alone. The thermodynamic equilibrium constant is also defined more accurately using activity...

thermodynamics: activity coefficient

Activity Coefficient in Ionic Solutions

Activity coefficient in ionic solutions describes how much a species behaves like its measured concentration. Activity is the effective concentration of a solute in solution. It equals the molar concentration multiplied by the activity coefficient, which is a unitless number. The activity coefficient depends on the total ionic strength of the solution. It shows how far a solution is from ideal behavior. When ionic strength is very low, the activity coefficient of an ionic species is close to...

chemical equilibria: redefining equilibrium constant

chemical-equilibria-redefining-equilibrium-constant

Salt Effect in Equilibrium Constant Calculations

Salt effect changes how a sparingly soluble salt dissolves when an inert salt is added. The size of this effect depends on the ionic strength of the solution. Ionic strength reflects how strongly the ions in the solution interact. In solution, the activity of a species is the product of its concentration and its activity coefficient. A redefined equilibrium constant must account for these activity effects when the ionic strength is moderately high. This form is also called the thermodynamic...

factors affecting activity coefficient

How Ionic Strength Changes Activity Coefficient

The activity coefficient of an ion in water depends on ionic strength, ion charge, and ion size. The extended Debye-Hückel equation describes these effects for aqueous solutions at 25°C. These three factors are partly linked, so changes in one can influence the others. When a solution has almost zero ionic strength, the activity coefficient is close to one. That means the solution behaves almost ideally. As ionic strength rises from 0 to 0.1 mol/L, the activity coefficient usually drops.

chemical equilibria: systematic approach to equilibrium calculations

Chemical equilibrium calculations become easier when they are organized around mass balance and charge balance. This approach is useful for systems with multiple equilibria, where several reactions must be considered together. It is especially helpful when finding the solubility of a sparingly soluble salt in water with a common ion present. The first step is to identify every chemical reaction in the system. Next, write the equilibrium constant expression for each reaction. These expressions...

acid&#8211;base equilibria: activity-based definition of ph

acidbase-equilibria-activity-based-definition-of-ph

How Ionic Strength Changes pH

pH depends on hydrogen ion activity, not just hydrogen ion concentration. In an ideal solution, pH is the negative logarithm of the hydrogen ion concentration. In a non-ideal solution, a more accurate pH uses hydrogen ion activity, which combines concentration with an activity coefficient. This difference matters most in very low ionic strength solutions, such as pure water. At first, the hydrogen ion activity coefficient is close to one. When an electrolyte that does not donate or accept a...

ladder diagrams: acid&#8211;base equilibria

Using Ladder Diagrams to Predict pH

Ladder diagrams help show how acid-base equilibria change with pH. They are graphical tools that make the chemistry of a system easier to read during analysis. In a ladder diagram, the vertical axis shows pH. Horizontal bars, or steps, place the pKa values in the system.

ladder diagrams: redox equilibria

Redox Potential Shifts in Ladder Diagrams

Ladder diagrams show redox equilibrium using electrochemical potential, E, as the vertical scale. They help students see how changes in concentration affect which species is most stable. The areas of predominance are set with the Nernst equation. A useful example is the Fe3+/Fe2+ half-reaction, which has a standard-state potential of +0.771 V. At potentials more positive than +0.771 V, Fe3+ predominates. At potentials more negative than +0.771 V, Fe2+ predominates. Ladder diagrams also show...

ladder diagrams: complexation equilibria

Reading Metal-Ligand Ladder Diagrams

Ladder diagrams help show equilibria in metal-ligand complexes. In these diagrams, the vertical scale shows pL, or the concentration of free ligand that has not reacted. The horizontal lines mark the log of formation constants and show which species is dominant in each region. For the Cd and ammonia system, the formation constant K1 for Cd(NH3)2+ is 3.55 × 10^2. Its log value is 2.55, so pNH3 = 2.55 is the dividing line between Cd2+ and Cd(NH3)2+ dominance. Above 2.55, Cd2+ is the predominant...

solubility equilibria: overview

How Solubility Reaches Equilibrium

Solubility equilibrium describes what happens when a sparingly soluble salt dissolves in water and then reaches a balance with the solid left over. In a saturated solution, dissolved ions and the undissolved solid are in dynamic equilibrium. The process is reversible, so this topic is also called precipitation equilibrium. This balance matters in real life. Sugar-rich foods can produce organic acids that dissolve hydroxyapatite, the mineral in tooth enamel, which can lead to tooth decay. A...

solubility equilibria: ionic product of water

solubility-equilibria-ionic-product-of-water

Water Ionization and Kw in Equilibrium

Water ionization and the ionic product of water describe how pure water reaches equilibrium. Water is a weak electrolyte, so only a small amount breaks into hydrogen ions and hydroxide ions. At a fixed temperature, the amount of undissociated water stays almost constant. Because of this, the ionic product of water is the product of the hydrogen ion concentration and the hydroxide ion concentration. It is written as K w . The square root of K w gives the concentration of each ion in pure water.

complexation equilibria: overview

Stepwise Metal-Ligand Complexation

Stepwise metal-ligand complexation forms coordination compounds when metal ions and ligands share electrons through dative, or coordinate covalent, bonds. In these reactions, the metal ion binds to one or more ligands until its coordination number is reached. This number tells how many bonds form between the metal ion and the ligands. In aqueous solution, many metal ions are already surrounded by water molecules. These species are called aqua complexes. Complexation reactions are described by...

complexation equilibria: the chelate effect

complexation-equilibria-the-chelate-effect

Chelating Ligands and Metal Complex Stability

Metal complexes form when metal atoms or cations interact with ligands in a complexation reaction. These donor-acceptor adducts are central to understanding how metal ions bind in chemistry. Ligands can bind in different ways. A monodentate ligand uses one donor site. A bidentate ligand uses two donor sites, and a polydentate ligand uses more than two. Ethylene diamine is a bidentate ligand that binds through two nitrogen donor atoms and forms a five-membered ring. Polydentate ligands can...

complexation equilibria: factors influencing stability of complexes

complexation-equilibria-factors-influencing-stability-of-complexes

Complex Ions: Metal and Ligand Stability

Complex ions form when a metal cation accepts electron pairs from ligands, which are the electron pair donors. The stability of these metal complexes depends mainly on the metal ion and on the ligands attached to it. The metal ion’s size and charge play a major role in stability. As the size of the metal ion increases, complex stability usually decreases when the valency of the metal ion and the ligands stays the same. As the charge on the metal ion increases, complex stability increases. <br...

redox equilibria: overview

Redox Electron Transfer and Half-Reactions

Redox reactions involve the transfer of electrons from one species to another. In this type of reaction, electrons are not shared between atoms. They move from the species that loses them to the species that gains them. The species that loses electrons is the reducing agent, also called the reductant. It is oxidized during the reaction. The species that gains electrons is the oxidizing agent, or oxidant, and it is reduced. Redox reactions are often written as two half-reactions. One...

titrimetric methods: types and commonly used strategies

titrimetric-methods-types-and-commonly-used-strategies

Direct, Back, and Displacement Titrations

Titrimetric methods use a standard solution to measure the amount of an analyte in chemistry. The main categories are volumetric, gravimetric, and coulometric methods. Each one reaches the endpoint in a different way. In volumetric titrations, the key measurement is the volume of a titrant with a known concentration. The titrant is added until it reacts completely with the analyte. In gravimetric titrations, the standard solution forms an insoluble precipitate with the analyte. That solid is...

classification of titrimetric analysis based on reaction types

classification-of-titrimetric-analysis-based-on-reaction-types

Four Reaction Types in Titrimetric Analysis

Titrimetric analysis measures solution volume and is also called volumetric analysis. A standard solution with a known concentration is placed in the burette and is called the titrant. The solution with an unknown concentration in the flask is the analyte, or titrand. Titrimetric analysis is grouped into four types based on the reaction between the titrant and the analyte. Acid-base titrations involve a neutralization reaction between an acid and a base. This reaction forms water molecules.

key terms and concepts

Learn a step-by-step method for solving equilibrium problems using reaction lists, K expressions, mass balance, charge balance, and approximation checks.

Equilibrium Calculations with Mass and Charge | JoVE K12

analytical chemistry

JoVE Core Analytical Chemistry simplifies complex chemical principles by breaking them down into clear, engaging animations, making topics from SI Units to NMR spectroscopy more accessible and straightforward. Additionally, the scientist-in-action videos highlight the application of these concepts in real-world research conducted in laboratories globally.

Arizona Science Standards

Physical Science

HS+C.P1

HS+C.P1U1.6

south-carolina-college-and-career-ready-science-standards

South Carolina College and Career Ready Science Standards

C-PS1-6

formula-mass-and-mole-concepts-of-compounds

Formula Mass and Mole Concepts of Compounds

Formula Mass of Covalent Compounds

Chemical formulas represent the elemental makeup of substances. For covalent compounds, the formula represents the ...

Expressing Solution Concentration

A solute is a component of a solution that is typically present at a much lower concentration than the solvent. Solute concentrations are often described ...

determining-the-mass-percent-composition-in-an-aqueous-solution

Determining the Mass Percent Composition in an Aqueous Solution

Source: Laboratory of Dr. Neal Abrams &#8212; SUNY College of Environmental Science and Forestry
Determining the composition of a solution is an important ...

Solutions and Concentrations

Source: Laboratory of Dr. Michael Evans &#8212; Georgia Institute of Technology
A solution is a homogeneous mixture containing some components in small ...

Reaction Stoichiometry

A balanced chemical equation provides a great deal of information in a very succinct format. Chemical formulas provide the identities of the reactants and ...

stoichiometry-product-yield-and-limiting-reactants

Stoichiometry, Product Yield, and Limiting Reactants

Chemical equations represent how a chemical reaction proceeds from reactants to products through physical or chemical change using chemical formulas.
...

Understand and be prepared to use values specific to chemical processes: the mole, molar mass, molarity, and percent composition. EXPLANATION: During the early and mid-1800s, a tremendous amount of early research poured into building an understanding of the way that atoms combine. This work required analysis of the percent composition of different substances. Joseph Proust's work with tin oxides led him to publish his law of definite proportions noting that a given pure substance will have a constant ratio for the combination of elements making up the substance. Building on Proust's work, John Dalton published his law of multiple proportions and atomic theory noting that multiple patterns exist for the way that atoms combine, yet the combining atoms are invariable. Meanwhile Amedeo Avogadro hypothesizes that given equal pressures and temperatures, two equal volumes of gas will contain equal numbers of atoms. Acknowledging that the exact number of atoms was unknown in these gaseous volumes, the Latin word "mole" was used. "Mole" translates to "lump" recognizing the ambiguous quantity of gas. A number of attempts have been undertaken historically to quantify the mole. Robert Millikan's oil drop experiment revealed the change of a single electron, which could then be divided into Faraday's Constant for the charge of a mole of electrons. Dividing the charge of a mole of electrons by the charge of a single electron yields the number of electrons in a mole, $6.022\times10^{\wedge}23$. Students should be familiar with how to translate between the given quantities. Student's first use atomism/Dalton's atomic theory in third grade noting that matter is made up of particles too small to be seen. This the first time where students will undertake the process of counting these invisible particles. Electrolysis of water provides a tangible experience to demonstrate the constituent parts of water, though the definite proportions of water may not be easily seen due to the solubility of the gasses produced. The concept of relative mass can be explored by comparing small groups of like items. For example, relative masses of beans can be compared with pinto, white, and black beans. If bags are created with equal numbers of like beans, students can develop a concept of why the smallest bean will have a relative mass of 1, analogous to hydrogen.

CHEM1.PS1.1

Chemical Equations

Chemical equations represent the identities and relative quantities of substances involved in a chemical reaction. The substances undergoing reaction are ...

The Atomic Theory of Matter

The earliest recorded discussion of the basic structure of matter comes from ancient Greek philosophers. Leucippus and Democritus argued that all matter ...

Chemical Reactions

A chemical reaction is a process by which the bonds in the atoms of substances are rearranged to generate new substances. Matter cannot be created or ...

Balancing Redox Equations

Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or ...

Demonstrate that atoms, and therefore mass, are conserved during a chemical reaction by balancing chemical reactions. EXPLANATION: Standard 7.PS1.4 explores the idea that chemical reactions are rearrangements of atoms, and students undertake the process of balancing chemical reactions with that standard in seventh grade. The introduction of molar masses in high school makes an explicit connection between the number of atoms, as previously investigated, and the actual masses of the atoms, permitting the collection of more concrete evidence for the conservation of mass in chemical reactions.

CHEM1.PS1.2

Reaction Yield

The theoretical yield of a reaction is the amount of product estimated to form based on the stoichiometry of the balanced chemical equation. The ...

A balanced chemical equation provides the information of chemical formulas of the reactants and products involved in the chemical change. A ...

Limiting Reactant

The relative amounts of reactants and products represented in a balanced chemical equation are often referred to as stoichiometric amounts. However, in ...

In systems with multiple equilibria, the equilibrium calculations use a systematic approach involving a series of steps to make sure there are as many ...

Perform stoichiometric calculations involving the following relationships: mole- mole; mass-mass; mole-mass; mole- particle; and mass- particle. Show a qualitative understanding of the phenomenon of percent yield, limiting, and excess reagents in a chemical reaction through pictorial and conceptual examples. (states of matter liquid and solid; excluding volume of gasses). EXPLANATION: This standard builds on the idea that balancing chemical reactions provides evidence for conservation of mass and that the behavior of atoms follows predictable patterns. Students now have the opportunity to utilize this understanding as they perform and evaluate chemical reactions. (The concepts of limiting reagent and percent yield are presented; however, students are not expected to determine these values algebraically. Use of molar volume in stoichiometric processes is beyond the scope of this standard.)

Predicting Reaction Outcomes

Kinetics describes the rate and path by which a reaction occurs. In contrast, thermodynamics deals with state functions and describes the properties, ...

Introduction to Chemical Reactions

All chemical reactions begin with a reactant, the general term for one or more substances entering the reaction. Sodium and chloride ions, for example, ...

Chemical Reactions in Aqueous Solutions

Chemical substances interact in many different ways. Certain chemical reactions exhibit common patterns of reactivity. Due to the vast number of chemical ...

Precipitation Reactions

In a precipitation reaction, aqueous solutions of soluble salts react to give an insoluble ionic compound &#x2013; the precipitate. The reaction occurs ...

Oxidation-Reduction Reactions

Oxidation&ndash;Reduction Reactions

Earth&rsquo;s atmosphere contains about 20% molecular oxygen, O2, a chemically reactive gas that plays an essential ...

Oxidation Numbers

In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the ...

Acids, Bases and Neutralization Reactions

An acid-base reaction is one in which a hydrogen ion, H+, is transferred from one chemical species to another. Such reactions are of central importance to ...

Synthesis and Decomposition Reactions

Synthesis and decomposition are two types of redox reactions. Synthesis means to make something, whereas decomposition means to break something. The ...

types-of-chemical-reactions-exchange-and-reversible

Types of Chemical Reactions: Exchange and Reversible

An exchange reaction is a chemical reaction in which both synthesis and decomposition occur, chemical bonds are both formed and broken, and chemical ...

Use the reactants in a chemical reaction to predict the products and identify reaction classes (synthesis, decomposition, combustion, single replacement, double replacement). EXPLANATION: Chemical reactions are rearrangements of atoms that follow predicable patterns. There are patterns both at the macroscopic level in the behavior of some of the reaction classes, as well as patterns in the rearrangements of the atoms underlying the reaction. Students should be able to predict the products of the reactions, which also requires the ability to recognize the general patterns for each type of reaction.

CHEM1.PS1.4

kinetic-molecular-theory-gas-laws-explain-properties-gas

Kinetic Molecular Theory and Gas Laws Explain Properties of Gas Molecules

The test of the kinetic molecular theory (KMT) and its postulates is its ability to explain and describe the behavior of a gas. The various gas laws ...

basic-postulates-kinetic-molecular-theory-particle-size-energy

Basic Postulates of Kinetic Molecular Theory: Particle Size, Energy, and Collision

The ideal-gas equation, which is empirical, describes the behavior of gases by establishing relationships between their macroscopic properties. For ...

Ideal Gas Law

Derivation of the Ideal Gas Law
Gases are a fundamental state of matter. A gas is a collection of molecules that have a significant distance between their ...

gas-laws-boyle-s-gay-lussac-charles-avogadro-s-and-ideal-gas-law

Gas Laws: Boyle's, Gay-Lussac, Charles', Avogadro's, and Ideal Gas Law

Through experiments, scientists established the mathematical relationships between pairs of variables, such as pressure and temperature, pressure and ...

kinetic-molecular-theory-molecular-velocities-temperature-kinetic

Kinetic Molecular Theory: Molecular Velocities, Temperature, and Kinetic Energy

The kinetic molecular theory qualitatively explains the behaviors described by the various gas laws. The postulates of this theory may be applied in a ...

Kinetic Theory of an Ideal Gas

A mole is defined as the amount of any substance that contains as many molecules as there are atoms in exactly 12 grams of carbon-12. An Italian scientist ...

applications-of-the-ideal-gas-law-molar-mass-density-and-volume

Applications of the Ideal Gas Law: Molar Mass, Density, and Volume

The volume occupied by one mole of a substance is its molar volume. The ideal gas law, PV = nRT, &nbsp;suggests that the volume of a given quantity of gas ...

Conduct investigations to explore and characterize the behavior of gasses (pressure, volume, and temperature), develop models to represent this behavior, and construct arguments to explain this behavior. Evaluate the relationship (qualitative and quantitatively) at STP between pressure and volume (Boyle's Law), temperature and volume (Charles' Law), temperature and pressure (Gay-Lussac Law) and moles and volume (Avogadro's Law), and evaluate and explain these relationships with respect to kinetic molecular theory. Be able to understand, establish, and predict the relationships between volume, temperature, and pressure using combined gas law both qualitatively and quantitatively. EXPLANATION: When exploring the behavior of gasses, it is important to consider experimental design. Experiments used to show the relationships between these sets of variables should include one independent and one dependent variable. Other variables should be held constant. Pressure should serve as the dependent variable because it cannot be manipulated directly. Avogadro's Law can be used to relate the amount of gas in two different containers in lieu of knowing actual number of gas particles in an individual container. Individual demonstrations can be performed to explore each of the different gas laws.

CHEM1.PS1.5

Ideal Gas Equation

The ideal gas equation is an equation of state that relates the state variables pressure, volume, temperature, and the number of moles of a hypothetical ...

Source: Laboratory of Dr. Andreas Z&#252;ttel - Swiss Federal Laboratories for Materials Science and Technology
The ideal gas law describes the behavior ...

real-gases-effects-intermolecular-forces-molecular-volume-deriving

Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation

Thus far, the ideal gas law, PV = nRT, has been applied to a variety of different types of problems, ranging from reaction stoichiometry and empirical and ...

chemical-stoichiometry-gases-using-ideal-gas-law-to-determine

Chemical Stoichiometry and Gases: Using Ideal Gas Law to Determine Moles

Chemical stoichiometry describes the quantitative relationships between reactants and products in chemical reactions.

In addition to measuring quantities ...

pV-Diagrams

The pV diagram, which is a graph of pressure versus volume of the gas under study, is helpful in describing certain aspects of the substance. When the ...

Use the ideal gas law, PV = nRT, to algebraically evaluate the relationship among the number of moles, volume, pressure, and temperature for ideal gases. EXPLANATION: If students have collected data during investigations for CHEM1.PS1.5, these data can then be used to linearize. With pressure assigned as the dependent variable and plotted against (moles) (temperature)/volume, the slope of the graph will be the gas constant, yielding the ideal gas law. After developing the mathematical model, this model can be used to make predictions for other systems.

CHEM1.PS1.6

Separation of Mixtures via Precipitation

Source: Laboratory of Dr. Ana J. Garc&#237;a-S&#225;ez &#8212; University of T&#252;bingen
Most samples of interest are mixtures of many different ...

States of Matter and Phase Changes

The internal energy of a substance&#8212;the total kinetic energy of all its molecules and the potential energy of their associated forces&#8212;depends ...

Distillation: Vapor&ndash;Liquid Equilibria

Distillation is a separation technique that takes advantage of the boiling point properties of disparate elements in a mixture. To perform distillation, ...

Filtration

Filtration is the physical separation of solids from a fluid using a filtration medium.
The filtration medium is chosen depending on the purpose of ...

Centrifugation

Centrifugation is a method of separating suspended particles from a liquid by spinning in a centrifuge at a high number of revolutions per minute.
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Analyze solutions to identify solutes and solvents, quantitatively analyze concentrations (molarity, percent composition, and ppm), and perform separation methods such as evaporation, distillation, and/or chromatography and show conceptual understanding of distillation. Construct argument to justify the use of certain separation methods under different conditions. EXPLANATION: In seventh grade, students developed an understanding that chemical and physical properties of a sample of matter could be used to identify a substance. Building on this understanding, students now explore the use of these physical and chemical properties to separate mixtures. Analysis of the substances is performed to aid in further discussion and facilitate further quantitative analysis.

CHEM1.PS1.7

Equilibrium Calculations with Mass and Charge

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