Electron Charge-to-mass Ratio

The electron charge-to-mass ratio, e/m, quantifies the magnitude of an electron’s electric charge relative to its mass and is a fundamental property in physics. It is determined by observing how an electron beam responds to known electric and magnetic fields: the fields accelerate or deflect the particles, while the resulting trajectory reveals the balance between electromagnetic force and inertial resistance. In the classic Thomson method, crossed fields first select a beam velocity, and a magnetic field then bends the beam into a measurable path. This measurement helped establish the electron as a subatomic particle and remains important in mass spectrometry, charged-particle optics, and accelerator physics.

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JoVE Science Education - Physics

Electric Charge in a Magnetic Field

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2023

Source: Andrew Duffy, PhD, Department of Physics, Boston University, Boston, MA This experiment duplicates J.J. Thomson's famous experiment at the end of the 19th century, in which he measured the charge-to-mass ratio of the electron. In combination with Robert A. Millikan's oil-drop experiment a few years later that produced a value for the charge of the electron, the experiments enabled scientists to find, for the first time, both the mass and the charge of the electron, which are key...

Ions and Ionic Charges

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2020

In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called ions. When...

Formal Charges

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2020

In some cases, there are seemingly more than one valid Lewis structures for molecules and polyatomic ions. The concept of formal charges can be used to help predict the most appropriate Lewis structure when more than one reasonable structure exists. Calculating Formal Charge The formal charge of an atom in a molecule is the hypothetical charge the atom would have if the electrons in the bonds are evenly distributed between the atoms. Alternatively, formal charge results when from the number...

Introduction to Mass Spectrometry

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2023

Source: Laboratory of Dr. Khuloud Al-Jamal - King's College London Mass spectrometry is an analytical chemistry technique that enables the identification of unknown compounds within a sample, the quantification of known materials, the determination of the structure, and chemical properties of different molecules. A mass spectrometer is composed of an ionization source, an analyzer, and a detector. The process involves the ionization of chemical compounds to generate ions. When using...

Atomic Radii and Effective Nuclear Charge

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2020

The elements in groups of the periodic table exhibit similar chemical behavior. This similarity occurs because the members of a group have the same number and distribution of electrons in their valence shells. Going across a period from left to right, a proton is added to the nucleus and an electron to the valence shell with each successive element. Going down the elements in a group, the number of electrons in the valence shell remains constant, but the principal quantum number increases by...

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