Dalibor Sames

Department of Chemistry, Columbia University

Affiliated withColumbia University Columbia College

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JoVE Journal Publications

ArticleTotal : 1	Year
Publication title Cited by 10	2009

Other Publications

Article	Year
Total synthesis of (-)-rhazinilam: asymmetric C[bond]H bond activation via the use of a chiral auxiliary. Journal of the American Chemical Society\| PubMed ID: 12059212	2002
Principles of mucin architecture: structural studies on synthetic glycopeptides bearing clustered mono-, di-, tri-, and hexasaccharide glycodomains. Journal of the American Chemical Society\| PubMed ID: 12175243	2002
C-C bond formation via C-H bond activation: synthesis of the core of teleocidin B4. Journal of the American Chemical Society\| PubMed ID: 12358522	2002
C-C bond formation via C-H bond activation: catalytic arylation and alkenylation of alkane segments. Journal of the American Chemical Society\| PubMed ID: 12418875	2002
Pt(IV)-catalyzed cyclization of arene-alkyne substrates via intramolecular electrophilic hydroarylation. Organic letters\| PubMed ID: 12659572	2003
Selective C-arylation of free (NH)-heteroarenes via catalytic C-H bond functionalization. Journal of the American Chemical Society\| PubMed ID: 12720429	2003
Reactivity of functional groups on the protein surface: development of epoxide probes for protein labeling. Journal of the American Chemical Society\| PubMed ID: 12837082	2003
Diversity synthesis via C-H bond functionalization: concept-guided development of new C-arylation methods for imidazoles. Journal of the American Chemical Society\| PubMed ID: 12940740	2003
Cobalt-catalyzed arylation of azole heteroarenes via direct C-H bond functionalization. Organic letters\| PubMed ID: 14507184	2003
Concise synthesis of the chemopreventitive agent (+/-)-deguelin via a key 6-endo hydroarylation. Organic letters\| PubMed ID: 14572247	2003
Fully synthetic carbohydrate-based vaccines in biochemically relapsed prostate cancer: clinical trial results with alpha-N-acetylgalactosamine-O-serine/threonine conjugate vaccine. Journal of clinical oncology : official journal of the American Society of Clinical Oncology\| PubMed ID: 14645418	2003
Ru(III)-catalyzed cyclization of arene-alkene substrates via intramolecular electrophilic hydroarylation. Organic letters\| PubMed ID: 14961628	2004
New tools for molecular imaging of redox metabolism: development of a fluorogenic probe for 3 alpha-hydroxysteroid dehydrogenases. Journal of the American Chemical Society\| PubMed ID: 14982413	2004
Cross-coupling of sp(3) C-H bonds and alkenes: catalytic cyclization of alkene-amide substrates. Journal of the American Chemical Society\| PubMed ID: 15161275	2004
Direct C-H bond arylation: selective palladium-catalyzed C2-arylation of N-substituted indoles. Organic letters\| PubMed ID: 15330642	2004
Oxidative C-arylation of free (NH)-heterocycles via direct (sp3) C-H bond functionalization. Journal of the American Chemical Society\| PubMed ID: 15479077	2004
Two-photon induced uncaging of a reactive intermediate. Multiphoton in situ detection of a potentially valuable label for biological applications. The Journal of organic chemistry\| PubMed ID: 15760198	2005
Site-specific phenylation of pyridine catalyzed by phosphido-bridged ruthenium dimer complexes: a prototype for C-H arylation of electron-deficient heteroarenes. Journal of the American Chemical Society\| PubMed ID: 15771470	2005
Design of optical switches as metabolic indicators: new fluorogenic probes for monoamine oxidases (MAO A and B). Journal of the American Chemical Society\| PubMed ID: 15796498	2005
Direct C-arylation of free (NH)-indoles and pyrroles catalyzed by Ar-Rh(III) complexes assembled in situ. Journal of the American Chemical Society\| PubMed ID: 15810815	2005
Selective and catalytic arylation of N-phenylpyrrolidine: sp3 C-H bond functionalization in the absence of a directing group. Journal of the American Chemical Society\| PubMed ID: 15826142	2005
Direct palladium-catalyzed C-2 and C-3 arylation of indoles: a mechanistic rationale for regioselectivity. Journal of the American Chemical Society\| PubMed ID: 15926829	2005
A new fluorogenic transformation: development of an optical probe for coenzyme Q. Organic letters\| PubMed ID: 15932212	2005
Room temperature hydroalkylation of electron-deficient olefins: sp3 C-H functionalization via a lewis acid-catalyzed intramolecular redox event. Journal of the American Chemical Society\| PubMed ID: 16131169	2005
Room temperature intramolecular hydro-O-alkylation of aldehydes: sp3 C-H functionalization via a Lewis acid catalyzed tandem 1,5-hydride transfer/cyclization. Organic letters\| PubMed ID: 16288523	2005
Fluoromorphic substrates for fatty acid metabolism: highly sensitive probes for mammalian medium-chain acyl-CoA dehydrogenase. Angewandte Chemie (International ed. in English)\| PubMed ID: 16365837	2006
Selective and catalytic arylation of N-phenylpyrrolidine: (sp3) C-H bond functionalization in the absence of a directing group [J. Am. Chem. Soc. 2005, 127, 5284-5285]. Journal of the American Chemical Society\| PubMed ID: 16506792	2006
Oxidative C-arylation of free (NH)-heterocycles via direct sp3 C-H bond functionalization [J. Am. Chem. Soc. 2004, 126, 13244-13246]. Journal of the American Chemical Society\| PubMed ID: 16506793	2006
C-H bond functionalization in complex organic synthesis. Science (New York, N.Y.)\| PubMed ID: 16601184	2006
Catalytic C-H arylation of SEM-protected azoles with palladium complexes of NHCs and phosphines. Organic letters\| PubMed ID: 16671761	2006
Phosphorylation state-responsive lanthanide peptide conjugates: a luminescence switch based on reversible complex reorganization. Organic letters\| PubMed ID: 16774241	2006
Fluorogenic metabolic probes for direct activity readout of redox enzymes: Selective measurement of human AKR1C2 in living cells. Proceedings of the National Academy of Sciences of the United States of America\| PubMed ID: 16938874	2006
Synthesis of luminescent heterometallic bis-lanthanide complexes via selective, sequential metallation. Chemical communications (Cambridge, England)\| PubMed ID: 17024267	2006
sp3 C-H bond arylation directed by amidine protecting group: alpha-arylation of pyrrolidines and piperidines. Journal of the American Chemical Society\| PubMed ID: 17076471	2006
Phosphine-free palladium-catalyzed C-H bond arylation of free (N-H)-indoles and pyrroles. The Journal of organic chemistry\| PubMed ID: 17288392	2007
Cocktails of Tb(3+) and Eu(3+) complexes: a general platform for the design of ratiometric optical probes. Journal of the American Chemical Society\| PubMed ID: 17518468	2007
Transposing molecular fluorescent switches into the near-IR: development of luminogenic reporter substrates for redox metabolism. Journal of the American Chemical Society\| PubMed ID: 17542585	2007
Ruthenium catalyzed decarbonylative arylation at sp3 carbon centers in pyrrolidine and piperidine heterocycles. Journal of the American Chemical Society\| PubMed ID: 17803274	2007
Harnessing functional plasticity of enzymes: a fluorogenic probe for imaging 17beta-HSD10 dehydrogenase, an enzyme involved in Alzheimer's and Parkinson's diseases. Journal of the American Chemical Society\| PubMed ID: 17958419	2007
A luminescent sensor for tyrosine phosphorylation. Organic letters\| PubMed ID: 18069839	2008
Imaging induction of cytoprotective enzymes in intact human cells: coumberone, a metabolic reporter for human AKR1C enzymes reveals activation by panaxytriol, an active component of red gins... Journal of the American Chemical Society\| PubMed ID: 18826220	2008
C-H bond functionalization via hydride transfer: Lewis acid catalyzed alkylation reactions by direct intramolecular coupling of sp3 C-H bonds and reactive alkenyl oxocarbenium intermediates. Journal of the American Chemical Society\| PubMed ID: 19099474	2009
C-H bonds as ubiquitous functionality: a general approach to complex arylated pyrazoles via sequential regioselective C-arylation and N-alkylation enabled by SEM-group transposition. Journal of the American Chemical Society\| PubMed ID: 19206533	2009
Fluorescent false neurotransmitters visualize dopamine release from individual presynaptic terminals. Science (New York, N.Y.)\| PubMed ID: 19423778	2009
C-H bond functionalization via hydride transfer: synthesis of dihydrobenzopyrans from ortho-vinylaryl akyl ethers. Organic letters\| PubMed ID: 19548698	2009
C-H bond functionalization via hydride transfer: direct coupling of unactivated alkynes and sp(3) C-H bonds catalyzed by platinum tetraiodide. Journal of the American Chemical Society\| PubMed ID: 19852462	2009
Development of pH-responsive fluorescent false neurotransmitters. Journal of the American Chemical Society\| PubMed ID: 20540519	2010
C-H bonds as ubiquitous functionality: a general approach to complex arylated imidazoles via regioselective sequential arylation of all three C-H bonds and regioselective N-alkylation enable... The Journal of organic chemistry\| PubMed ID: 20608749	2010
(-)-CHANA, a fluorogenic probe for detecting amyloid binding alcohol dehydrogenase HSD10 activity in living cells. ACS chemical biology\| PubMed ID: 20836522	2010
Expanding the use of fluorogenic enzyme reporter substrates to imaging metabolic flux changes: the activity measurement of 5Î±-steroid reductase in intact mammalian cells. ACS chemical biology\| PubMed ID: 20863068	2010
Intermolecular energy transfer from Tb3+ to Eu3+ in aqueous aggregates and on the surface of human cells. Organic letters\| PubMed ID: 21563789	2011
C-H arylation of pyridines: high regioselectivity as a consequence of the electronic character of C-H bonds and heteroarene ring. Journal of the American Chemical Society\| PubMed ID: 21939181	2011