Robert H. Grubbs

Robert H. Grubbs

Division of Chemistry and Chemical Engineering, California Institute of Technology

Affiliated withCalifornia Institute of Technology

Research Area

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JoVE Journal Publications

ArticleTotal : 1
Year
An <em>In Vitro</em> Enzymatic Assay to Measure Transcription Inhibition by Gallium(III) and H<sub>3</sub> 5,10,15-tris(pentafluorophenyl)corroles
Publication title

Cited by 1

2015

Other Publications

Article
Year
Highly Active Metathesis Catalysts Generated In Situ from Inexpensive and Air-Stable Precursors J.L. acknowledges the National Institute of Health for a postdoctoral fellowship. We thank Chr...

Angewandte Chemie (International ed. in English)| PubMed ID: 11169728

2001
2001
2001
Effects of Olefin Substitution on the Ring-Closing Metathesis of Dienes.

The Journal of organic chemistry| PubMed ID: 11671845

1997
1998
1998
Synthesis of Catenane Structures via Ring-Closing Metathesis.

The Journal of organic chemistry| PubMed ID: 11674608

1999
2002
Ring expansion via olefin metathesis.

Journal of the American Chemical Society| PubMed ID: 11916403

2002
2002
2002
2002
Formal vinyl C[bond]H activation and allylic oxidation by olefin metathesis.

Angewandte Chemie (International ed. in English)| PubMed ID: 12207379

2002
An "endless" route to cyclic polymers.

Science (New York, N.Y.)| PubMed ID: 12242440

2002
Synthesis of A,B-alternating copolymers by ring-opening-insertion-metathesis polymerization.

Angewandte Chemie (International ed. in English)| PubMed ID: 12386864

2002
2002
2002
2003
2003
Controlled living ring-opening-metathesis polymerization by a fast-initiating ruthenium catalyst.

Angewandte Chemie (International ed. in English)| PubMed ID: 12707895

2003
2003
2003
2003
Magic ring rotaxanes by olefin metathesis.

Angewandte Chemie (International ed. in English)| PubMed ID: 12876744

2003
Synthesis, structure, and activity of enhanced initiators for olefin metathesis.

Journal of the American Chemical Society| PubMed ID: 12914474

2003
2003
2004
Decomposition of a key intermediate in ruthenium-catalyzed olefin metathesis reactions.

Journal of the American Chemical Society| PubMed ID: 15198568

2004
The exclusivity of multivalency in dynamic covalent processes.

Angewandte Chemie (International ed. in English)| PubMed ID: 15213952

2004
A stable four-membered N-heterocyclic carbene.

Journal of the American Chemical Society| PubMed ID: 15315404

2004
2005
Highly selective 1,3-isomerization of allylic alcohols via rhenium oxo catalysis.

Journal of the American Chemical Society| PubMed ID: 15740106

2005
Light-adjustable lens: development of in vitro nomograms.

Transactions of the American Ophthalmological Society| PubMed ID: 15747746

2004
Magic ring catenation by olefin metathesis.

Organic letters| PubMed ID: 15901151

2005
Template-directed olefin cross metathesis.

Organic letters| PubMed ID: 16146390

2005
A general model for selectivity in olefin cross metathesis.

Journal of the American Chemical Society| PubMed ID: 16220959

2003
Prevention of undesirable isomerization during olefin metathesis.

Journal of the American Chemical Society| PubMed ID: 16332044

2005
Highly active chiral ruthenium catalysts for asymmetric ring-closing olefin metathesis.

Journal of the American Chemical Society| PubMed ID: 16464082

2006
Highly active water-soluble olefin metathesis catalyst.

Journal of the American Chemical Society| PubMed ID: 16536510

2006
2006
Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture).

Angewandte Chemie (International ed. in English)| PubMed ID: 16724297

2006
Model compounds of ruthenium-alkene intermediates in olefin metathesis reactions.

Journal of the American Chemical Society| PubMed ID: 16802789

2006
Rate acceleration in olefin metathesis through a fluorine-ruthenium interaction.

Journal of the American Chemical Society| PubMed ID: 16953611

2006
2006
Highly active chiral ruthenium catalysts for asymmetric cross- and ring-opening cross-metathesis.

Angewandte Chemie (International ed. in English)| PubMed ID: 17054302

2006
Monofunctional metathesis polymers via sacrificial diblock copolymers.

Angewandte Chemie (International ed. in English)| PubMed ID: 17075932

2006
2006
Template-directed one-step synthesis of cyclic trimers by ADMET.

Journal of the American Chemical Society| PubMed ID: 17131986

2006
2006
2007
2007
2007
2006
Light-adjustable lens: customizing correction for multifocality and higher-order aberrations.

Transactions of the American Ophthalmological Society| PubMed ID: 17471323

2006
2007
Decomposition of ruthenium olefin metathesis catalysts.

Journal of the American Chemical Society| PubMed ID: 17547403

2007
Double C--H activation of an N-heterocyclic carbene ligand in a ruthenium olefin metathesis catalyst.

Angewandte Chemie (International ed. in English)| PubMed ID: 17549783

2007
Small-molecule N-heterocyclic-carbene-containing olefin-metathesis catalysts for use in water.

Angewandte Chemie (International ed. in English)| PubMed ID: 17549784

2007
2007
2007
2007
Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes.

Angewandte Chemie (International ed. in English)| PubMed ID: 17623287

2007
Hyperbranched macromolecules via olefin metathesis.

Journal of the American Chemical Society| PubMed ID: 17902678

2007
2007
The catalytic asymmetric total synthesis of elatol.

Journal of the American Chemical Society| PubMed ID: 18163634

2008
2008
Well-defined liquid crystal gels from telechelic polymers.

Journal of the American Chemical Society| PubMed ID: 18197667

2008
2008
Ruthenium carbene complexes bearing an anionic carboxylate chelated to a hemilabile ligand.

Chemistry (Weinheim an der Bergstrasse, Germany)| PubMed ID: 18236478

2008
Oxygen-atom transfer from carbon dioxide to a Fischer carbene at (PNP)Ir.

Journal of the American Chemical Society| PubMed ID: 18410098

2008
A facile preparation of imidazolinium chlorides.

Organic letters| PubMed ID: 18412354

2008
2008
Ruthenium-olefin complexes: effect of ligand variation upon geometry.

Chemistry (Weinheim an der Bergstrasse, Germany)| PubMed ID: 18481833

2008
2008
2008
2008
End capping ring-opening olefin metathesis polymerization polymers with vinyl lactones.

Journal of the American Chemical Society| PubMed ID: 18646851

2008
Cyclic ruthenium-alkylidene catalysts for ring-expansion metathesis polymerization.

Journal of the American Chemical Society| PubMed ID: 18729450

2008
2009
2009
Ring-expansion metathesis polymerization: catalyst-dependent polymerization profiles.

Journal of the American Chemical Society| PubMed ID: 19199611

2009
2009
2009
2009
Effects of NHC-backbone substitution on efficiency in ruthenium-based olefin metathesis.

Journal of the American Chemical Society| PubMed ID: 19351207

2009
2008
2009
Switching and extension of a [c2]daisy-chain dimer polymer.

Journal of the American Chemical Society| PubMed ID: 19728719

2009
Arene-perfluoroarene interactions as physical cross-links for hydrogel formation.

Angewandte Chemie (International ed. in English)| PubMed ID: 19750666

2002
Tunable, temperature-responsive polynorbornenes with side chains based on an elastin peptide sequence.

Angewandte Chemie (International ed. in English)| PubMed ID: 19784987

2009
2009
2009
2010
2010
2010
The Living ROMP of trans-Cyclooctene.

Macromolecules| PubMed ID: 20379393

2009
Nonproductive events in ring-closing metathesis using ruthenium catalysts.

Journal of the American Chemical Society| PubMed ID: 20518557

2010
2010
2010
Insights into the carbene-initiated aggregation of [Fe(cot)(2)].

Angewandte Chemie (International ed. in English)| PubMed ID: 21110365

2011
2010
2011
2011
2011
2011
Highly selective ruthenium metathesis catalysts for ethenolysis.

Journal of the American Chemical Society| PubMed ID: 21510645

2011
2010
Chelated ruthenium catalysts for Z-selective olefin metathesis.

Journal of the American Chemical Society| PubMed ID: 21563826

2011
2011
Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis.

Journal of the American Chemical Society| PubMed ID: 21574621

2011
Synthesis and direct imaging of ultrahigh molecular weight cyclic brush polymers.

Angewandte Chemie (International ed. in English)| PubMed ID: 21591042

2011
2010
Z-selective homodimerization of terminal olefins with a ruthenium metathesis catalyst.

Journal of the American Chemical Society| PubMed ID: 21649443

2011
2011
2011
2011
EPR study of spin labeled brush polymers in organic solvents.

Journal of the American Chemical Society| PubMed ID: 22023139

2011
2011
Improved ruthenium catalysts for Z-selective olefin metathesis.

Journal of the American Chemical Society| PubMed ID: 22097946

2012
2012
Cis-selective ring-opening metathesis polymerization with ruthenium catalysts.

Journal of the American Chemical Society| PubMed ID: 22239675

2012
Thermally Stable, Latent Olefin Metathesis Catalysts.

Organometallics| PubMed ID: 22282652

2011
Decomposition pathways of Z-selective ruthenium metathesis catalysts.

Journal of the American Chemical Society| PubMed ID: 22500642

2012
2013
2012
2012
2012
2012
Rapid self-assembly of brush block copolymers to photonic crystals.

Proceedings of the National Academy of Sciences of the United States of America| PubMed ID: 22912408

2012
Precisely tunable photonic crystals from rapidly self-assembling brush block copolymer blends.

Angewandte Chemie (International ed. in English)| PubMed ID: 22976479

2012
Concise syntheses of insect pheromones using Z-selective cross metathesis.

Angewandte Chemie (International ed. in English)| PubMed ID: 23055437

2013
2013
2013
Practical and general palladium-catalyzed synthesis of ketones from internal olefins.

Angewandte Chemie (International ed. in English)| PubMed ID: 23325587

2013
2012
2013
Z-Selective ethenolysis with a ruthenium metathesis catalyst: experiment and theory.

Journal of the American Chemical Society| PubMed ID: 23547887

2013
2013
2013
2013
Alkene chemoselectivity in ruthenium-catalyzed Z-selective olefin metathesis.

Angewandte Chemie (International ed. in English)| PubMed ID: 23832646

2013
2013
Aldehyde-selective Wacker-type oxidation of unbiased alkenes enabled by a nitrite co-catalyst.

Angewandte Chemie (International ed. in English)| PubMed ID: 24039135

2013
Highly ordered dielectric mirrors via the self-assembly of dendronized block copolymers.

Journal of the American Chemical Society| PubMed ID: 24093537

2013
Photolithographic olefin metathesis polymerization.

Journal of the American Chemical Society| PubMed ID: 24171659

2013
2013
Formal Anti-Markovnikov Hydroamination of Terminal Olefins.

Chemical science (Royal Society of Chemistry : 2010)| PubMed ID: 24327829

2014
Catalyst-controlled Wacker-type oxidation: facile access to functionalized aldehydes.

Journal of the American Chemical Society| PubMed ID: 24410719

2014
Catalytic, enantioselective synthesis of 1,2-anti-diols by asymmetric ring-opening/cross-metathesis.

Angewandte Chemie (International ed. in English)| PubMed ID: 24554613

2014
2014
2014
2014
2014
2014
Enantioselective olefin metathesis with cyclometalated ruthenium complexes.

Journal of the American Chemical Society| PubMed ID: 25137310

2014
Ru-Based Z-Selective Metathesis Catalysts with Modified Cyclometalated Carbene Ligands.

Chemical science (Royal Society of Chemistry : 2010)| PubMed ID: 25346842

2014
2014
Aerobic palladium-catalyzed dioxygenation of alkenes enabled by catalytic nitrite.

Angewandte Chemie (International ed. in English)| PubMed ID: 25376666

2015
2014
2014
Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis.

Angewandte Chemie (International ed. in English)| PubMed ID: 25522160

2015
2015
Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins.

Chemical science (Royal Society of Chemistry : 2010)| PubMed ID: 25722847

2014