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[(DPEPhos)(bcp)Cu]PF6
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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Article DOI: 10.3791/59739-v • 09:12 min • May 21st, 2019
May 21st, 2019 •
1, 1, 1, 1,2, 1, 2, 1
1Laboratoire de Chimie Organique, Service de Chimie et PhysicoChimie Organiques, Université libre de Bruxelles (ULB), 2Laboratoire de Chimie Organique et Photochimie, Service de Chimie et PhysicoChimie Organiques, Université libre de Bruxelles (ULB)

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Detailed and general protocols are presented for the synthesis of [(DPEPhos)(bcp)Cu]PF6, a general copper-based photoredox catalyst, and for its use in synthetic chemistry for the direct arylation of C-H bonds in (hetero)arenes and radical cyclization of organic halides.

Tags

DPEPhos Bcp Cu PF6 Photoredox Catalyst Radical Processes Sustainable Toxic Reagents Photoredox Catalysis Light-responsive Compound Visible Light Catalytic Cycle Ruthenium Complexes Iridium Complexes Non-noble Metals Copper-based Photoredox Catalysts Synthesis Synthetic Applications Chemical Synthesis Photocatalysis
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