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对金属有机骨架进行光谱测量的技术指南
对金属有机骨架进行光谱测量的技术指南
JoVE Journal
Chemistry
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JoVE Journal Chemistry
A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

对金属有机骨架进行光谱测量的技术指南

Full Text
3,125 Views
10:13 min
April 28, 2023

DOI: 10.3791/65072-v

Daniel R. Cairnie1, Amanda J. Morris1

1Department of Chemistry,Virginia Polytechnic and State Institute

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Please note that some of the translations on this page are AI generated. Click here for the English version.

在这里,我们使用聚合物稳定剂来制备金属有机框架(MOF)悬浮液,其基态和瞬态吸收光谱的散射显着降低。通过这些MOF悬浮液,该协议提供了各种指南,以光谱学表征MOF以产生可解释的数据。

通常,测量光如何与金属有机框架(MOF)相互作用,很难实现其高度散射的性质。该协议是制备可测量样品的简单有效的指南,用于高度有洞察力的光谱技术。该过程松散地基于先前使用聚合物稳定的胶体半导体的系统。

因此,它可以应用于需要材料悬浮的各种系统。该过程的最大问题是需要将其调整为 MOF 类型。最好的方法是系统地筛选此过程的 MIF 变量。

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