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JoVE Journal
Chemistry
基于高通量方法的等网状Al(III)膦酸盐基金属有机骨架化合物的发现与合成优化
基于高通量方法的等网状Al(III)膦酸盐基金属有机骨架化合物的发现与合成优化
JoVE Journal
Chemistry
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JoVE Journal Chemistry
Discovery and Synthesis Optimization of Isoreticular Al(III) Phosphonate-Based Metal-Organic Framework Compounds Using High-Throughput Methods

基于高通量方法的等网状Al(III)膦酸盐基金属有机骨架化合物的发现与合成优化

Full Text
3,974 Views
07:20 min
October 6, 2023

DOI: 10.3791/65441-v

Marvin Radke1, Ralf Suren1, Norbert Stock1

1Department of Inorganic Chemistry,Kiel University

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Please note that some of the translations on this page are AI generated. Click here for the English version.

Summary

靶向合成新的金属有机框架(MOFs)是困难的,它们的发现取决于化学家的知识和创造力。高通量方法可以快速有效地探索复杂的合成参数场,从而加快寻找晶体化合物和识别合成和结构趋势的过程。

Transcript

我认为元素周期表是一个巨大的游乐场,在我们的研究中,我们专注于新材料的合成,多孔材料,比如这里。这是一个结构模型,我们看到框架中的漏洞。这可以用来储存分子,也可以根据分子的大小分离分子。

除了这类研究,我们还开发新的反应堆系统,以加速发现过程。当前的实验挑战是使用额外的高通量仪器(例如高通量吸收表征设备)进一步加速合成和表征过程。出版物中缺乏关于影响重现性的合成和表征程序的细节是化学界一个众所周知的问题。

通过提供对我们的方法和设置的全面描述,我们旨在鼓励其他小组采用所描述的方法,从而提高实验研究的可重复性。我们不知道未来会带来什么,因为我们致力于发现新材料,我们永远不知道这些材料将具有什么样的特性。尽管如此,我认为使用来自可再生原料的连接分子将发挥重要作用。

关于应用,在气体分子的传感和分离中的使用将非常重要。

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