Chemical Reaction Rates

Chemical reaction rates describe how quickly reactants are converted into products, providing a quantitative view of change in chemical systems and a useful connection between chemistry and physics. Reaction rate depends on the frequency and energy of molecular collisions: increasing concentration or temperature can promote more effective collisions, while catalysts lower the activation energy without being consumed. Rate laws and kinetic measurements help researchers determine reaction mechanisms, model dynamic systems, and control industrial and biological processes. In physics, these principles support the study of molecular motion, energy transfer, transport phenomena, and nonequilibrium behavior.

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JoVE Core - Chemistry

Reaction Rate

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2020

The rate of reaction is the change in the amount of a reactant or product per unit time. Reaction rates are therefore determined by measuring the time dependence of some property that can be related to reactant or product amounts. Rates of reactions that consume or produce gaseous substances, for example, are conveniently determined by measuring changes in volume or pressure. The mathematical representation of the change in the concentration of reactants and products, over time, is the rate...

Factors Influencing the Rate of Chemical Reactions

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2023

A variety of factors influence the rate of chemical reactions. For a chemical reaction to happen, atoms must collide with enough energy to overcome the repulsion between their electrons. This energy is called activation energy. Factors influencing the rate of reaction either lower the activation energy or increase the likelihood of a successful collision. Concentration and Pressure: The more particles present within a given space, the more likely those particles are to bump into one another.

Chemical Reactions

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2019

A chemical reaction is a process by which the bonds in the atoms of substances are rearranged to generate new substances. Matter cannot be created or destroyed in a chemical reaction—the same type and number of atoms that make up the reactants are still present in the products. Merely, the rearrangement of chemical bonds produces new compounds. Chemical Reactions Rearrange Atoms into New Substances A chemical reaction takes starting materials—the reactants—and changes them into different...

Determining Rate Laws and the Order of Reaction

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2023

Source: Laboratory of Dr. Neal Abrams — SUNY College of Environmental Science and Forestry All chemical reactions have a specific rate defining the progress of reactants going to products. This rate can be influenced by temperature, concentration, and the physical properties of the reactants. The rate also includes the intermediates and transition states that are formed but are neither the reactant nor the product. The rate law defines the role of each reactant in a reaction and can be used to...

Temperature Dependence on Reaction Rate

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2020

The Collision Theory Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. This premise is the basis for a theory that explains many observations regarding chemical kinetics, including factors affecting reaction rates. The collision theory is based on the postulates that (i) the reaction rate is proportional to the rate of reactant collisions, (ii) the reacting species collide in an orientation allowing contact between...

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