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Accessing Valuable Ligand Supports for Transition Metals

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Article DOI: 10.3791/55366-v 09:45 min March 20th, 2017
March 20th, 2017



Reliable, intermediate scale preparation of 1,2,3,4,5-pentamethylcyclopentadiene (Cp*H) is presented. The revised protocol for the synthesis and purification of the ligand minimizes the need for specialized laboratory equipment while simplifying reaction workups and product purification. Use of Cp*H in the synthesis of [Cp*MCl2]2 complexes (M = Ru, Ir) is also described.


Keyword Extraction: 1,2,3,4,5-Pentamethylcyclopentadiene CP Star H Organo-metallic Chemistry Intermediate Scale Synthesis Lithium Hexanes Schlenk Line Argon Gas Paper Towels Scissors Tongs Water
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