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Controla la polimerización de apertura de Photoredox de O- Carboxyanhydrides mediada por complejos de Ni/Zn
Controlled Photoredox Ring-Opening Polymerization of <em>O</em>-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Controla la polimerización de apertura de Photoredox de O- Carboxyanhydrides mediada por complejos de Ni/Zn

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8,008 Views

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05:48 min

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November 21, 2017

DOI:

10.3791/56654-v

DOI:
10.3791/56654-v

•

05:48 min
November 21, 2017

•

2 Views
,
1Center for Molecular Systems and Organic Devices, Institute of Optoelectronic Materials, Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials,Nanjing University of Posts and Telecommunications, 2Department of Chemical Engineering,Virginia Polytechnic Institute and State University

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Summary

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Se presenta un protocolo para la polimerización de apertura controlada photoredox de O- carboxyanhydrides mediada por complejos de Ni/Zn.

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Controlled Photoredox Ring-opening PolymerizationO-carboxyanhydridesNi/zn ComplexesPoly(alpha-hydroxy Acids)High Molecular Weight PolyestersSide Chain Functional GroupsAnhydrous THFBipy-nickel(COD)Zinc Bis(hmds)Benzyl AlcoholIridium CatalystL1 MonomerBlue LED LightTemperature Control

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Cite this Article

Feng, Q., Tong, R. Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes. J. Vis. Exp. (129), e56654, doi:10.3791/56654 (2017).

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