Boron Trifluoride

Boron trifluoride is a colorless, highly reactive inorganic compound composed of boron and fluorine, widely studied in chemistry because of its strong Lewis acidity. Its electron-deficient boron atom accepts electron pairs from donor molecules, forming coordination complexes such as boron trifluoride etherate; the molecule itself has a trigonal planar structure. In organic synthesis, boron trifluoride promotes reactions including ether cleavage, alkylation, and polymerization by activating oxygen-containing or unsaturated substrates. Because it reacts readily with water to produce corrosive products, its handling requires dry conditions and appropriate protective measures, while its controlled reactivity supports applications in catalysis and chemical manufacturing.

Boron Trifluoride - Related Videos

Research

JoVE Journal - Chemistry

Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis

0 Views •

Cited by 5 •

2016

A protocol is described for the characterization of the key electrochemical parameters of a boron doped diamond (BDD) electrode and subsequent application for in situ pH generation experiments.

Negative Additive Manufacturing of Complex Shaped Boron Carbides

0 Views •

Cited by 9 •

2018

A method called negative additive manufacturing is used to produce near fully dense complex shaped boron carbide parts of various length scales. This technique is possible via the formulation of a novel suspension involving resorcinol-formaldehyde as a unique gelling agent that leaves behind a homogenous carbon sintering aid after pyrolysis.

Qualitative Identification of Carboxylic Acids, Boronic Acids, and Amines Using Cruciform Fluorophores

0 Views •

2013

Cross-conjugated cruciform fluorophores based on 1,4-distyryl-2,5-bis(arylethynyl)benzene and benzobisoxazole nuclei can be used to qualitatively identify diverse Lewis acidic and Lewis basic analytes. This method relies on the differences in emission colors of the cruciforms that are observed upon analyte addition. Structurally closely related species can be distinguished from each other.

Education

JoVE Core - Chemistry

Lewis Acids and Bases

0 Views •

2020

In 1923, G. N. Lewis proposed a generalized definition of acid-base behavior in which acids and bases are identified by their ability to accept or to donate a pair of electrons and form a coordinate covalent bond. A coordinate covalent bond (or dative bond) occurs when one of the atoms in the bond provides both bonding electrons. For example, a coordinate covalent bond occurs when a water molecule combines with a hydrogen ion to form a hydronium ion. A coordinate covalent bond also results when...

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides

0 Views •

Cited by 3 •

2018

Here, we present protocols for the synthesis of disaccharide nucleosides by the regioselective O-glycosylation of ribonucleosides via a temporary protection of their 2',3'-diol moieties utilizing a cyclic boronic ester. This method applies to several unprotected nucleosides such as adenosine, guanosine, cytidine, uridine, 5-methyluridine, and 5-fluorouridine to give corresponding disaccharide nucleosides.

View All Results

FAQs

Related Topics