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Engineering
ポリマー系ナノ複合材料の誘電特性向上のためのカップリング剤の応用
ポリマー系ナノ複合材料の誘電特性向上のためのカップリング剤の応用
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JoVE Journal Engineering
Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites

ポリマー系ナノ複合材料の誘電特性向上のためのカップリング剤の応用

Full Text
6,393 Views
06:34 min
September 19, 2020

DOI: 10.3791/60916-v

Haotian Li1,2,3, Dong Zhang4, Zechen Li4, Leyi Li5, Jiachen Liu1, Yugui Li1,2

1Taiyuan University of Science and Technology, 2Heavy Machinery Engineering Research Center of the Ministry of Education, 3Laboratory of Magnetic and Electric Functional Materials and Applications,The Key Laboratory of Shanxi Province, 4Beijing Institute of Aerospace System Engineering, 5Department of Electrical and Information Engineering,Sichuan College of Architectural Technology

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Overview

This study presents a low-cost solution-casting process to enhance the compatibility between polymer matrices and surface modified BaTiO3 fillers. The method effectively improves the energy density of polymer-based nanocomposites.

Key Study Components

Area of Science

  • Polymer Science
  • Nanocomposites
  • Energy Storage Materials

Background

  • Surface modification of ceramic fillers can enhance their compatibility with polymer matrices.
  • Improved wettability at the ceramic-polymer interface is crucial for performance.
  • High-performance film capacitors require flexible composite materials.
  • Commercial coupling agents can be used to modify ceramic nanofillers.

Purpose of Study

  • To develop a method for improving the energy storage performance of polymer-based nanocomposites.
  • To investigate the effects of coupling agents on the properties of ceramic-polymer interfaces.
  • To provide a cost-effective solution for producing flexible composites.

Methods Used

  • Preparation of KH550 solution with ethanol-water solvent.
  • Ultrasonication treatment of BaTiO3 nanoparticles in KH550 solutions.
  • Coating of BT nanoparticles with varying amounts of coupling agent.
  • Evaporation of solvent at controlled temperatures in a vacuum oven.

Main Results

  • Good wettability was achieved at the ceramic-polymer interface.
  • Enhanced energy storage performances were observed with optimal coupling agent amounts.
  • The method is suitable for the preparation of flexible composites.
  • Results indicate potential applications in high-performance film capacitors.

Conclusions

  • The developed solution-casting process is effective and low-cost.
  • Surface modification significantly improves composite performance.
  • This approach can facilitate advancements in energy storage technologies.

Frequently Asked Questions

What is the main focus of this study?
The study focuses on enhancing the compatibility of polymer-based nanocomposites using surface modified BaTiO3 fillers.
How does surface modification affect energy storage?
Surface modification improves wettability and enhances the energy storage performance of the composites.
What method was used for the surface modification?
A commercial coupling agent was used to modify the surface of the ceramic nanofillers.
What are the potential applications of this research?
The research has potential applications in the production of high-performance film capacitors.
Is the method described cost-effective?
Yes, the solution-casting process is described as simple and low-cost.

ここでは、表面修飾BaTiO3 フィラーを用いて、充填剤とポリマーベースのナノコンポジットのマトリックスとの間の相溶性を改善するための、シンプルで低コストのソリューション鋳造プロセスを実証し、複合材料のエネルギー密度を効果的に高めることができる。

市販のカップリング剤を用いることでセラミックナノフィラーの表面を改変できることが証明され、セラミックポリマー界面での良好な濡れ性が達成され、適切な量のカップリング剤によりエネルギー貯蔵性能が向上した。この研究によって開発された方法は、高性能フィルムコンデンサの製造に非常に望ましい柔軟な複合材料の調製に使用することができます。KH550の溶液を15分超超音波処理で95重量%エタノール水溶媒で調製します。

KH550ソリューションのBTナノ粒子を30分超超音波処理で治療します。このプロセスでは、KH550およびBTナノ粒子フィラーの重量を測定し、KH550希釈液中のカップリング剤の1、2、3、4、および5重量%を5ミリリットルの体積で測定します。80°Cのマトリックスから水エタノール溶媒を5時間蒸発させ、次いで真空オーブンで120°Cに120度にします。

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