Synthetic Polymers

Synthetic polymers are human-made macromolecules composed of repeating molecular units, or monomers, and they are central to modern chemistry because their structures can be tailored for specific properties. They form through polymerization, in which monomers join by chain-growth or step-growth reactions to produce long molecules with controlled molecular weight, branching, and cross-linking. Chemists adjust monomer selection and reaction conditions to influence strength, flexibility, thermal stability, solubility, and chemical resistance. These materials support applications ranging from packaging, coatings, and adhesives to fibers, biomedical devices, and advanced composites, while ongoing research seeks more sustainable feedstocks, recyclable designs, and polymers with improved performance.

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JoVE Journal - Chemistry
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MALDI-ToF MS Method for the Characterization of Synthetic Polymers with Varying Dispersity and End Groups

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2025

This protocol provides detailed instructions and examples for sample preparation, data acquisition, and data analysis to characterize synthetic polymers with varying dispersity and end-groups using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry.

Education

JoVE Core - Physical Chemistry

Classification and Mechanical Properties of Synthetic Polymers

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2026

Synthetic polymers are classified as elastomers, fibers, or plastics based on their crystallinity. Crystallinity, the degree of long-range order in the solid state, influences the mechanical properties (stretching or contracting) of elastomers. Elastomers are flexible polymers that can expand or contract easily upon the application of an external force. They have numerous crosslinks that pull them back into their original shape when stress is removed. Silicones, for instance, are highly elastic...

Polymers

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2020

The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the properties that they exhibit. Additionally,...

Synthetic Biology

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2023

This video presents synthetic biology and its role in bioengineering. Synthetic biology refers to the methods used to genetically modify organisms in order to make them capable of producing large quantities of a product. This product could be a protein that the cell already makes or a new protein that has been encoded in a newly-inserted DNA sequence. Here, we discuss how an organism's genetic material is modified using transformation or transfection. Then, the process is shown in the...

Chromogenic Polymer Hydrogel-Based Enzyme Screening Assay: A High Throughput Method to Screen the Carbohydrate-Active Enzymes Using Synthetic Substrates

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2025

In this video, we demonstrate a high throughput assay for carbohydrate-active enzyme screening using insoluble chromogenic polymer hydrogel substrates. The enzyme degrades these substrates into a soluble colored product that can be quantified by measuring the color intensity of the product.

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