Transition Elements

Transition elements are metallic elements whose atoms or common ions have a partially filled d subshell, giving them distinctive chemical and physical behavior. Their d-electron configurations allow electrons to occupy different energy levels and participate in bonding, so these elements commonly show variable oxidation states, colored compounds, magnetic properties, and coordination-complex formation. In chemistry, these behaviors help explain trends across the periodic table and the reactivity of compounds such as metal complexes. Transition elements also serve as catalysts because they can bind reactants and provide accessible oxidation states, supporting industrial synthesis, environmental chemistry, biological processes, and materials research.

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JoVE Core - Chemistry

Periodic Classification of the Elements

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2020

The periodic table arranges atoms based on increasing atomic number so that elements with the same chemical properties recur periodically. When their electron configurations are added to the table, a periodic recurrence of similar electron configurations in the outer shells of these elements is observed. Because they are in the outer shells of an atom, valence electrons play the most important role in chemical reactions. The outer electrons have the highest energy of the electrons in an atom...

Properties of Transition Metals

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2020

Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals. Figure 1: Periodic Table. The transition metals are located in groups 3–11 of the periodic table. The inner transition metals are in the two rows...

Phase Transitions

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2020

Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to occupy...

Classification of Elements and Compounds

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2020

Pure substances consist of only one type of matter. A pure substance can be an element or a compound. An element consists of only one type of atom, while a compound consists of two or more types of atoms held together by a chemical bond. Elements are classified as atomic or molecular based on the nature of their basic units. Compounds are pure substances composed of two or more elements in fixed, definite proportions. Compounds are classified as ionic or molecular (covalent) based on the bonds...

Cooperative Allosteric Transitions

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2020

Cooperative allosteric transitions can occur in multimeric proteins, where each subunit of the protein has its own ligand-binding site. When a ligand binds to any of these subunits, it triggers a conformational change that affects the binding sites in the other subunits; this can change the affinity of the other sites for their respective ligands. The ability of the protein to change the shape of its binding site is attributed to the presence of a mix of flexible and stable segments in the...

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