Measurement Uncertainty

Measurement uncertainty is the quantified doubt associated with a measured value, indicating the range within which the true value is expected to lie. In chemistry, it arises from random variation, systematic effects, instrument resolution, calibration, sampling, and procedural limitations; repeated measurements help estimate random uncertainty, while uncertainty propagation combines contributions from calculations and multiple measurements. Reporting results with an appropriate uncertainty, rather than as a single exact number, supports meaningful comparison with reference values and acceptance criteria. This principle is essential for evaluating analytical methods, assessing significant figures, validating instruments, interpreting experimental results, and communicating the reliability of chemical measurements.

Measurement Uncertainty - Related Videos

Education

JoVE Core - Chemistry

Uncertainty in Measurement: Reading Instruments

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2020

Counting is the type of measurement that is free from uncertainty, provided the number of objects being counted does not change during the process. Such measurements result in exact numbers. By counting the eggs in a carton, for instance, one can determine exactly how many eggs are there in the carton. Similarly, the numbers of defined quantities are also exact. For example, 1 foot is exactly 12 inches, 1 inch is exactly 2.54 centimeters, and 1 gram is exactly 0.001 kilograms. Quantities...

Uncertainty in Measurement: Significant Figures

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2020

All the digits in a measurement, including the uncertain last digit, are called significant figures or significant digits. Note that zero may be a measured value; for example, if a scale that shows weight to the nearest pound reads “140,” then the 1 (hundreds), 4 (tens), and 0 (ones) are all significant (measured) values. A measurement result is properly reported when its significant digits accurately represent the certainty of the measurement process. Below are a set of rules to determine the...

Uncertainty in Measurement: Accuracy and Precision

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2020

Scientists typically make repeated measurements of a quantity to ensure the quality of their findings and to evaluate both the precision and the accuracy of their results. Measurements are said to be precise if they yield very similar results when repeated in the same manner. A measurement is considered accurate if it yields a result that is very close to the true or the accepted value. Precise values agree with each other; accurate values agree with a true value. Suppose a quality control...

The Uncertainty Principle

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2020

Werner Heisenberg considered the limits of how accurately one can measure properties of an electron or other microscopic particles. He determined that there is a fundamental limit to how accurately one can measure both a particle’s position and its momentum simultaneously. The more accurate the measurement of the momentum of a particle is known, the less accurate the position at that time is known and vice versa. This is what is now called the Heisenberg uncertainty principle. He mathematically...

Research

JoVE Journal - Behavior

Experimental Research Examining How People Can Cope with Uncertainty Through Soft Haptic Sensations

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Cited by 4 •

2015

To date research has focused on cognitive strategies people adopt to cope with uncertainty. This research examines instead an experiential way of dealing with uncertainty and introduces a set of experimental methods showing how the experience of haptic softness can serve as a tool to deal with uncertainty.

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