Solid To Gas

The solid-to-gas transition, known as sublimation, is a phase change in which a substance moves directly from a solid to a gas without becoming a liquid, making it an important concept in chemistry and materials science. The process occurs when particles in a solid absorb enough energy to overcome intermolecular attractions, while the surrounding pressure and temperature allow the gaseous phase to form directly; the reverse process is deposition. Sublimation helps explain the behavior of dry ice and certain crystals, and it supports freeze-drying, purification of compounds, and analytical sample preparation. Understanding this transition also clarifies phase diagrams and vapor-pressure relationships.

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Education

JoVE Science Education - Engineering

Gas Absorber

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2023

Source: Michael G. Benton and Kerry M. Dooley, Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA Gas absorbers are used to remove contaminants from gas streams. Multiple designs are used to accomplish this objective1. A packed bed column uses gas and liquid streams running counter to each other in a column packed with loose packing materials, such as ceramics, metals, and plastics, or structured packing1. The packed bed uses surface area created by the packing to...

Solid Phase Synthesis

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2023

Source: Vy M. Dong and Diane Le, Department of Chemistry, University of California, Irvine, CA Merrifield's solid-phase synthesis is a Nobel Prize winning invention where a reactant molecule is bound on a solid support and undergoes successive chemical reactions to form a desired compound. When the molecules are bound to a solid support, excess reagents and byproducts can be removed by washing away the impurities, while the target compound remains bound to the resin. Specifically, we will...

Ideal Gas Law

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2023

Source: Laboratory of Dr. Andreas Züttel - Swiss Federal Laboratories for Materials Science and Technology The ideal gas law describes the behavior of most common gases at near-ambient conditions and the tendency of all chemical matter in the dilute limit. It is a fundamental relationship between three measurable macroscopic system variables (pressure, temperature, and volume) and the number of molecules of gas in the system, and is therefore an essential link between the microscopic and the...

Solid-Liquid Extraction

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2023

Source: Laboratory of Dr. Jay Deiner — City University of New York Extraction is a crucial step in most chemical analyses. It entails removing the analyte from its sample matrix and passing it into the phase required for spectroscopic or chromatographic identification and quantification. When the sample is a solid and the required phase for analysis is a liquid, the process is called solid-liquid extraction. A simple and broadly applicable form of solid-liquid extraction entails combining the...

Metallic Solids

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2020

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties. All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...

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