Heat Equation

The heat equation is a partial differential equation that describes how temperature changes through space and time, making it fundamental to thermal analysis in engineering and physics. It models the diffusion of thermal energy through a material, with the rate of temperature change governed by thermal conductivity, density, specific heat, and boundary conditions; its formulation follows from energy conservation and Fourier’s law of heat conduction. Engineers use the equation to predict transient and steady-state temperature fields in structures, electronics, manufacturing systems, and energy devices. These predictions guide material selection, thermal management, safety assessment, and system design.

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JoVE Core - Chemistry
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Thermochemical Equations

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2020

For a chemical reaction (the system) carried out at constant pressure – with the only work done caused by expansion or contraction – the enthalpy of reaction (also called the heat of reaction, ΔHrxn) is equal to the heat exchanged with the surroundings (qp). The change in enthalpy is an extensive property, and it depends on the amounts of the reactants participating in the reaction (or the number of moles of reactants). The change in enthalpy is specific to the reaction, and the physical...

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JoVE Science Education - Engineering

Testing the Heat Transfer Efficiency of a Finned-tube Heat Exchanger

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2023

Source: Michael G. Benton and Kerry M. Dooley, Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA Heat exchangers transfer heat from one fluid to another fluid. Multiple classes of heat exchangers exist to fill different needs. Some of the most common types are shell and tube exchangers and plate exchangers1. Shell and tube heat exchangers use a system of tubes through which fluid flows1. One set of tubes contains the liquid to be cooled or heated, while the second...

Clausius-Clapeyron Equation

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2020

The equilibrium between a liquid and its vapor depends on the temperature of the system; a rise in temperature causes a corresponding rise in the vapor pressure of its liquid. The Clausius-Clapeyron equation gives the quantitative relation between a substance’s vapor pressure (P) and its temperature (T); it predicts the rate at which vapor pressure increases per unit increase in temperature. where ΔHvap is the enthalpy of vaporization for the liquid, R is the gas constant, and A is a constant...

Chemical Equations

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2020

Chemical equations represent the identities and relative quantities of substances involved in a chemical reaction. The substances undergoing reaction are called reactants, and their formulas are placed on the left side of the equation. The substances generated by the reaction are called products, and their formulas are placed on the right side of the equation. Plus signs (+) separate individual reactant and product formulas, and an arrow (→) separates the reactant and product (left and right)...

The Nernst Equation

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2020

Nonstandard Reaction Conditions The interconnection between standard cell potentials and various thermodynamic parameters such as the standard free energy change ΔG° and equilibrium constant K has been previously explored. For example, a redox reaction involving zinc(II) and tin(II) ions at 1 M concentration with Eºcell = +0.291 V and ΔG° = −56.2 kJ is spontaneous. Discharge of this cell, however, results in a change in the reactant concentration and a steady decrease of the cell potential. At...

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