5.2
The Reaction Gibbs Energy
Based on the reaction Gibbs energy, ΔrG, reactions or processes can be categorized into two types: exergonic and endergonic.
Exergonic reactions are characterized by a negative ΔrG value, indicating that they are spontaneous in the forward direction and can be used to make other reactions easier.
For example, in biological cells, the oxidation of carbohydrates into simpler molecules provides energy, which is used for various biological activities.
Reactions with positive ΔrG values are called endergonic reactions. A common example is the conversion of glucose to glucose-6-phosphate.
Now, consider a reversible reaction where ‘a’ moles of A and ‘b’ moles of B react to form 'c' moles of C and 'd ' moles of D.
For this reaction, the standard reaction Gibbs energy, ΔrG°, is the difference between the sum of the standard molar Gibbs energies of the products and that of the reactants, each multiplied by their respective stoichiometric coefficients.
As ΔrG = 0 at equilibrium, ΔrG° can be measured using its relationship with the reaction quotient, Q, where Q depends on the activities of the reactants and products.
The reaction Gibbs energy (ΔrG) is a crucial parameter that determines whether a reaction will occur spontaneously or not. It can be used to categorize reactions into two types: exergonic and endergonic.
Exergonic reactions are those in which ΔrG is less than zero. This implies that these reactions can occur spontaneously without an external input of energy. In biological systems, a typical example of an exergonic reaction is the oxidation of carbohydrates. This reaction produces simple molecules, and the energy released can be harnessed to drive other processes, such as the formation of proteins from amino acids, brain activity, and muscle contractions.
On the other hand, endergonic reactions have a positive ΔrG value. These reactions require an external input of energy to occur. As a result, they are often referred to as work-consuming reactions. A typical example of an endergonic reaction in biology is the conversion of glucose to glucose-6-phosphate.
Now, consider a reversible chemical reaction where 'a' moles of A and 'b' moles of B react to form 'c' moles of C and 'd 'moles of D. The standard reaction Gibbs energy (ΔrG°) is defined as the difference between the standard molar Gibbs energies of the products and reactants, considering their stoichiometric coefficients in the given reaction.
ΔrG varies with the composition of the system. For this reaction, the relative amounts of products and reactants present at any point in the reaction can be given by the reaction quotient ‘Q’. The reaction quotient also considers the activities of the reactants (A and B) and products (C and D).
In essence, the Gibbs energy and its changes provide valuable insights into the thermodynamics of chemical reactions, helping us understand why some reactions occur spontaneously while others require energy input.
Based on the reaction Gibbs energy, ΔrG, reactions or processes can be categorized into two types: exergonic and endergonic.
Exergonic reactions are characterized by a negative ΔrG value, indicating that they are spontaneous in the forward direction and can be used to make other reactions easier.
For example, in biological cells, the oxidation of carbohydrates into simpler molecules provides energy, which is used for various biological activities.
Reactions with positive ΔrG values are called endergonic reactions. A common example is the conversion of glucose to glucose-6-phosphate.
Now, consider a reversible reaction where ‘a’ moles of A and ‘b’ moles of B react to form 'c' moles of C and 'd ' moles of D.
For this reaction, the standard reaction Gibbs energy, ΔrG°, is the difference between the sum of the standard molar Gibbs energies of the products and that of the reactants, each multiplied by their respective stoichiometric coefficients.
As ΔrG = 0 at equilibrium, ΔrG° can be measured using its relationship with the reaction quotient, Q, where Q depends on the activities of the reactants and products.
From Chapter 5:
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5.2 : The Reaction Gibbs Energy
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