Deleterious Substances in Aggregate

Organic impurities like decayed vegetative matter interfere with cement hydration and prevent good bonding between aggregate and cement paste. A colorimetric test detects organic matter by measuring solution darkness after agitation—darker solutions indicate higher organic content. This poor bonding compromises concrete strength and durability significantly.

Fine impurities coat aggregate particles and weaken bonding and strength of aggregate with cement paste. They increase the surface area requiring more water for mixing, placing, and finishing. Excess water increases drying shrinkage and cracking likelihood, reducing concrete durability and long-term performance.

Excess salt, particularly above 6% by mass, corrodes steel reinforcements embedded in concrete and compromises structural integrity. Salt also absorbs moisture from air, causing efflorescence—white deposits on concrete surfaces. Washing aggregates with fresh water reduces salt content and prevents these serious durability issues.

Low-density materials and soft inclusions such as shale, clay lumps, coal, or wood break down under loads, leading to pitting and popouts in concrete. These particles are non-durable and may absorb water, causing aggregate degradation. ASTM C 33-03 sets permissible levels for such unsound particles to ensure quality.

The wet sieve method determines fine impurities in coarse aggregates by separating particles based on size and density. Sedimentation methods also assess clay and silt content effectively. These testing approaches help identify deleterious substances and ensure aggregate quality meets construction standards and specifications.

The colorimetric test involves agitating aggregate in solution and observing the resulting color intensity. Darker solutions indicate higher organic matter content, while lighter solutions suggest lower contamination levels. This simple visual assessment helps engineers quickly evaluate aggregate quality and suitability before concrete production begins.

Washing aggregates with fresh water removes deleterious substances, particularly excess salts that cause reinforcement corrosion and efflorescence. This cleaning process reduces moisture content and bulking of aggregate, improving bonding with cement paste and enhancing overall concrete durability, strength, and long-term performance.