Journal
/
/
高价碘鎓炔基三氟甲磺酸酯的生成Cyanocarbenes的合成应用
JoVE Journal
Chemistry
Author Produced
A subscription to JoVE is required to view this content.  Sign in or start your free trial.
JoVE Journal Chemistry
Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
DOI:

12:27 min

September 08, 2013

, ,

Chapters

  • 00:00Title
  • 03:46Synthesis of Phenyl HIAT
  • 05:35Synthesis of n-Pentyl HIAT
  • 08:33O-H insertion cyanocarbene reaction using Phenyl HIAT
  • 10:17Cylcopropanation cyanocarbene reaction using Phenyl HIAT
  • 11:50Conclusion

Summary

Automatic Translation

本文中所描述的合成,分离,和超价碘炔基三氟甲磺酸酯(HIATs)反应,用叠氮化物,以产生cyanocarbenes。该程序将涉及空气敏感和制冷剂的技术,包括在惰性气氛下冷过滤。处理的合成的化合物及安全性也将被讨论。

Related Videos

Read Article