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Chemistry
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用电动势技术测定碱土金属合金的热力学性质
JoVE Journal
Chemistry
This content is Free Access.
JoVE Journal
Chemistry
Determination of Thermodynamic Properties of Alkaline Earth-liquid Metal Alloys Using the Electromotive Force Technique
Please note that all translations are automatically generated.
Click here for the English version.
用电动势技术测定碱土金属合金的热力学性质
DOI:
10.3791/56718-v
•
12:02 min
•
November 03, 2017
•
Thomas P. Nigl
,
Nathan D. Smith
,
Timothy Lichtenstein
,
Jarrod Gesualdi
,
Kuldeep Kumar
,
Hojong Kim
1
Department of Materials Science and Engineering
,
The Pennsylvania State University
Chapters
00:05
Title
00:47
Binary CaF
2
-BaF
2
Electrolyte Fabrication
03:58
Ba-Bi Alloy Electrode Fabrication and Electrical Lead Assembly
06:00
Electrochemical Cell Assembly and Electrochemical Measurements
09:35
Results: Electromotive Force Measurements of Ba-Bi(x
Ba
= 0.05)|CaF
2
-BaF
2
|Ba-Bi(x
Ba
= 0.05, 0.10, 0.20) and Ba(s)|CaF
2
-BaF
2
|Ba-Bi(x
Ba
= 0.05-0.25)
11:23
Conclusion
Summary
Automatic Translation
English (Original)
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Automatic Translation
本协议描述了在高温 (723-1、123 K) 的液态金属合金中碱土金属元素的电动势的测量, 以确定其热力学性质, 包括活性、部分摩尔熵、部分摩尔焓, 和相变温度, 在广泛的组成范围。
Tags
Thermodynamic Properties
Alkaline Earth-liquid Metal Alloys
Electromotive Force Technique
Activity
Partial Molar Entropy
Partial Molar Enthalpy
Binary Alloy Systems
Calcium Fluoride
Barium Fluoride
Yttria-stabilized Zirconia
Polyvinyl Alcohol
Electrolyte Mixture
Pellet
Tapping Holes
Electrolyte Cap
Article
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