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Ring Current Effects in Aromatic NMR
Description
Ring current effects in aromatic and antiaromatic compounds change how protons appear in NMR. In aromatic molecules such as benzene, the circulation of (4n + 2) pi-electrons creates a diamagnetic, or diatropic, ring current around the outside of the ring. This current makes the magnetic field weaker inside the ring and stron...
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Transcript
In aromatic compounds, the circulation of (4n + 2) π-electrons sets up a diamagnetic or diatropic ring current around their perimeters.
This current induces a magnetic field that opposes the external field inside the ring and reinforces it on the outside.
So, the protons in benzene are deshielded and exhibit high chemica...
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