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Chemistry

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Analytical Chemistry

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Interpreting Nuclear Magnetic Resonance Spectra

Reading Hydrogen Counts in 13C DEPT Spectra

Description

13C DEPT spectra help chemists read how many hydrogens are attached to each carbon in a molecule. In proton-coupled carbon-13 spectra, broadband proton decoupling simplifies the signal, but it also removes information about the attached protons. DEPT, or distortionless enhancement by polarization transfer, restores that kind...

Transcript

When carbon-13 spectra are simplified by broadband proton decoupling, structural information regarding the attached hydrogens is lost.

Distortionless enhancement by polarization transfer, or DEPT, is a double resonance technique that distinguishes carbons by the number of attached protons.

The DEPT experiment utilizes a complex pul...

Tags

DEPT NMRCarbon-13 NMRProton-Coupled SpectraBroadband DecouplingDEPT-45 SpectrumDEPT-90 SpectrumDEPT-135 SpectrumMethyl Methylene MethineQuaternary CarbonsStructure Elucidation