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Journal / Chemistry / Photogeneration av N-hetrosyklisk Carbenes:…
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Photogeneration av N-hetrosyklisk Carbenes
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Photogeneration av N-hetrosyklisk Carbenes: programmet i Photoinduced Ring-åpning Metathesis polymerisering

Article DOI: 10.3791/58539-v • 12:19 min • November 29th, 2018
November 29th, 2018 •
1, 1, 1, 2,3, 2,3, 2,3, 4, 4
1ICGM, Université de Montpellier, CNRS, ENSCM, 2Institut de Science des Matériaux de Mulhouse (IS2M UMR 7361 CNRS), Université de Haute-Alsace, 3Université de Strasbourg, 4Laboratoire de Chimie des Polymères Organiques (LCPO UMR 5629 ENSCBP), Université de Bordeaux

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Vi beskriver en protokoll for å photogenerate N-hetrosyklisk carbenes (NHCs) ved UV bestråling av en 2-isopropylthioxanthone/imidazolium tetraphenylborate salt system. Metoder for å karakterisere photoreleased NHC og belyse fotokjemisk mekanismen er foreslått. Protokollene for ring-åpning metathesis photopolymerization i løsningen og miniemulsion illustrerer potensialet i dette 2-komponent NHC photogenerating systemet.

Tags

Kjemi problemet 141 Polymer ring-åpning metathesis BOLTRE carbene NHC fotokjemi miniemulsion photolysis photoreactor photoreactivity
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