Uio-66 Mof

UiO-66 is a zirconium-based metal-organic framework (MOF), a porous crystalline material in which metal clusters connect organic linkers to create tunable internal spaces. In its structure, zirconium oxide clusters coordinate with terephthalate linkers, producing a three-dimensional network with high surface area, chemical stability, and adjustable defects or pore environments. These features allow UiO-66 MOF to adsorb and separate molecules, support heterogeneous catalysis, and serve as a platform for sensing and pollutant removal. Its robust framework also makes it useful for studying structure-property relationships and designing materials for selective separations, chemical reactions, and environmental applications.

Uio-66 Mof - Related Videos

Research

JoVE Journal - Bioengineering

Synthesis, Hemoglobin Encapsulation and Biorthogonal PEGylation in Hierarchically Porous UiO-66 Nanoparticles for Oxygen Delivery Applications

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2026

This protocol details the synthesis, hemoglobin encapsulation, and surface PEGylation of hierarchically porous UiO-66 nanoparticles designed for oxygen delivery. The procedure combines defect engineering with strain-promoted biorthogonal conjugation to generate highly permeable and physiologically stable carriers suitable for biomedical applications.

Assembly of Porous Monolithic Materials Using a Pickering Emulsion Strategy Stabilized by Metal–Organic Framework (MOF) Particles

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2026

This study successfully uses MIL-96(Al) Metal-Organic Frameworks particles to stabilize Pickering emulsions, which serve as templates to form mechanically robust, hierarchically porous monolithic materials. This method allows scalable MOF shaping while preserving crystal integrity. Tuning formulation is key to controlling pore size, interconnectivity, permeability, and robustness.

Solvothermal Synthesis of MIL-96 and UiO-66-NH2 on Atomic Layer Deposited Metal Oxide Coatings on Fiber Mats

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Cited by 9 •

2018

Metal-organic frameworks are effective in gas storage and heterogeneous catalysis, but typical synthesis methods result in loose powders that are difficult to incorporate into smart materials. We demonstrate a method of first coating fabrics with ALD metal oxides, resulting in conformal films of MOF on the fabrics during solvothermal synthesis.

Research

JoVE Journal - Chemistry
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In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework

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Cited by 14 •

2020

The use of FTIR spectroscopy for investigation of the surface properties of polycrystalline solids is described. Preparation of sample pellets, activation procedures, characterization with probe molecules and model studies of CO2 adsorption are discussed.

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)

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Cited by 1 •

2020

Here, we present a protocol for active site validation of metal-organic framework catalysts by comparing stoichiometric and catalytic carbonyl-ene reactions to find out whether a reaction takes place on the inner or outer surface of metal-organic frameworks.

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