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TOPICAL COLLECTIONS

Metal-Organic Framework Synthesis and Characterization

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Guest Editor

Seth Cohen

Seth Cohen

University of California, San Diego

<p>Seth M. Cohen is a Professor and former Chair of the Department of Chemistry and Biochemistry at the University of California, San Diego.&nbsp; Prof. Cohen began his education by obtaining a Bachelor of Science degree in Chemistry and a Bachelor of Arts degree in Political Science from Stanford University. &nbsp;Upon completion of his undergraduate education, Prof. Cohen attended graduate school at the University of California, Berkeley where he studied bioinorganic chemistry under the guidance of Prof. Kenneth N. Raymond. &nbsp;After completing his PhD&nbsp;at U.C. Berkeley, he moved to Boston&nbsp;to perform an NIH postdoctoral fellowship in the laboratory of Prof. Stephen J. Lippard at the Massachusetts Institute of Technology. &nbsp;Upon completion of his postdoctoral work, Prof. Cohen moved to his present position at UC&nbsp;San Diego. &nbsp;His research interests are in the areas of inorganic, bioinorganic, medicinal, and materials chemistry.&nbsp; His laboratory has made several contributions to the synthesis, post-synthetic modification, and preparation of polymer composites of metal-organic frameworks (MOFs).&nbsp; Prof. Cohen is a fellow of the American Association for the Advancement of Science (AAAS), the American Chemical Society (ACS), and the Royal Society of Chemistry (RSC). &nbsp;His research and teaching accomplishments have been recognized by the Cottrell Scholar Award from the RCSA and the Arthur C. Cope Scholar Award from the ACS.</p>

Collection Overview

Metal-organic frameworks (MOFs) are among the most widely studied solid-state materials in modern chemistry. Most synthesis and characterization studies on MOFs have been performed by inorganic chemists. Although the field has reached a reasonable level of maturity over the last ~20 years, there are still subtleties to the synthesis, modification, and characterization of MOFs that may elude the non-expert. This puts physical chemists, materials scientists, and others outside of the core inorganic discipline at a disadvantage when trying to study MOFs. A collection of JoVE video articles will help researchers, especially those outside the core inorganic chemistry discipline, obtain better access to MOFs and their proper characterization, to help enable their own innovative studies. This is critical, as many of the most important investigations of MOFs are presently focused on their applications, and hence access to these materials by a broader scientific community will be very valuable. 


This Topical Collection on MOFs would nominally include visualized experiments on the synthesis of MOFs (using different methods), the post-synthetic modification of MOFs, the formation of MOF composites (with polymers, biomolecules), and the characterization of MOFs using some of the most important methods such as gas sorption (e.g., surface area and pore size distributions), powder X-ray diffraction (PXRD), thermal gravimetric analysis (TGA), and electron microscopy (e.g., SEM and TEM). In sum, the collection would endeavor to provide detailed procedures for many of the most important synthesis and characterization methods to enable scientists to prepare and study their own, high-quality MOF materials.

Articles

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
5:26

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

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Cited by 2

2023

Abstracts

Shaping of Metal Organic Framework as monolith by Pickering emulsion

Michael Carboni*1

1French Atomic Commission (CEA)