3.1: Structure of Alkanes

The formation of carbon-carbon bonds leading to the creation of the carbon chain is the basis of organic chemistry. August Kekulé and Archibald Scott Couper independently developed this idea of carbon chain formation.

Hydrocarbons are the simplest organic compounds composed of carbons and hydrogens. Based on the bond order between carbons, the hydrocarbons are further classified into alkanes, alkenes, and alkynes.

Alkanes are the simplest hydrocarbons with sp³ hybrid carbon atoms. These sp³ carbon atoms can form sigma bonds with sp³ orbitals of other carbon atoms or with the 1s atomic orbitals of hydrogen atoms. Since alkanes possess only single bonds between carbon atoms, they are also known as saturated hydrocarbons. The general formula of alkanes is C_nH_2n+2, indicating that for every "n" carbon atom, alkanes have "2n+2" hydrogen atoms.

The Lewis structure of alkanes can be simplified using the condensed structural formula. In this representation, bonds between carbon-hydrogen and carbon-carbon are omitted to simplify the structure. Further simplification is done with the help of the line-angle formula. The lines represent carbon-carbon bonds. The line end and vertex represent the carbon atoms. The hydrogens are not explicitly shown and are assumed to be present, satisfying the carbon valency.

Compounds containing carbon and hydrogen atoms are called hydrocarbons. The simplest hydrocarbon, methane, has a tetravalent carbon atom bonded to four hydrogen atoms.

If one of the hydrogen atoms of methane is replaced with a carbon atom bonded to three hydrogen atoms, the next hydrocarbon, ethane, is formed.

Methane and ethane belong to the family of hydrocarbons called alkanes. Since alkanes contain only single covalent bonds, they are saturated hydrocarbons.

In any alkane, for example ethane, the carbon atoms are sp³ hybridized, making them tetrahedral carbons. These singly occupied hybrid orbitals overlap with the sp³ hybrid orbitals of the neighboring carbon atom to form a carbon-carbon sigma bond.

The other hybrid orbitals of carbon form sigma bonds with the 1s orbitals of each of the hydrogen atoms. The bonded atoms are at an angle of 109.5° to each other.

Examine the structures of three simple alkanes — methane, ethane, and propane. Methane, CH₄, has one carbon and four hydrogen atoms; ethane, C₂H₆, has two carbons and six hydrogen atoms; and propane, C₃H₈, has three carbons and eight hydrogen atoms.

Notice that each succeeding formula has one carbon and two hydrogens — namely, a CH₂ group more than the preceding formula.

In general, for every n number of carbon atoms, there will be 2n+2 hydrogen atoms. Thus, alkanes have the characteristic molecular formula: C_nH_2n+2.

A condensed structural formula simplifies the Lewis structure of alkanes by omitting the bonds to hydrogens or even carbon-carbon bonds.

Hydrocarbons can also be represented using line-angle or skeletal structures. The lines denote carbon-carbon bonds, with each vertex and endpoint implying a carbon atom. The hydrogens, although not explicitly shown, are assumed to be bonded to the carbons, satisfying their valency.

• Alkanes - Simplest organic compounds, composed of carbons and hydrogens.
• Structural formula of alkanes - Represents bonds between carbon and hydrogen in alkanes.
• Cnh2n+2 general formula - It indicates that for every n carbon atom, alkanes have 2n+2 hydrogen atoms.
• Condensed structural formula alkanes - Simplifies Lewis structure by omitting bonds between carbon-hydrogen and carbon-carbon.
• Saturated Hydrocarbons - Another name for Alkanes, as they possess only single bonds.

• Define Alkanes - Explain what they are (e.g., Alkanes are simplest organic compounds).
• Contrast structural formula vs condensed structural formula - Explain key differences (e.g., Bonds omission).
• Explore Hydrocarbons - Describe the different types (e.g., Alkanes).
• Explain Saturated Hydrocarbons - Describe why alkanes are considered saturated.
• Apply Alkanes structural formula - Breakdown of its formula (e.g., c for carbon and n for number of carbon atoms).

• What are alkanes and their general formula?
• What does Structural formula of alkanes represent?
• What are Saturated Hydrocarbons and why are alkanes considered saturated?

• Students – Understand how the concept of Alkanes supports student understanding in organic chemistry.
• Educators – Provides a clear framework to help in teaching the topic of Alkanes, their structures, and properties.
• Researchers – Relevance for scientific study or methodology around organic compounds and hydrocarbons.
• Chemistry Enthusiasts – Offers insights into organic compound structures, broadening interest and curiosity.