Lithium Water Reaction

The lithium water reaction is an exothermic redox process in which lithium metal reacts with water to form lithium hydroxide and hydrogen gas, illustrating the reactivity of alkali metals. Lithium atoms lose electrons to become Li+ ions, while water is reduced and combines to produce hydroxide ions and H2, according to 2Li + 2H2O → 2LiOH + H2. The reaction provides a clear laboratory example of electron transfer, alkaline solution formation, and periodic trends in metal reactivity. Observing gas evolution and heat release also helps students connect chemical equations with reaction hazards and experimental safety.

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Research

JoVE Journal - Chemistry

1,3,5-Triphenylbenzene and Corannulene as Electron Receptors for Lithium Solvated Electron Solutions

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Cited by 4 •

2016

The authors report on conductivity studies carried out on lithium solvated electron solutions (LiSES) prepared using 1,3,5-triphenylbenzene (TPB) and corannulene as electron receptors.

Construction and Testing of Coin Cells of Lithium Ion Batteries

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Cited by 13 •

2012

A protocol to construct and test coin cells of lithium ion batteries is described. The specific procedures of making a working electrode, preparing a counter electrode, assembling a cell inside a glovebox and testing the cell are presented.

In Situ Neutron Powder Diffraction Using Custom-made Lithium-ion Batteries

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Cited by 7 •

2014

We describe the design and construction of an electrochemical cell for the examination of electrode materials using in situ neutron powder diffraction (NPD). We briefly comment on alternate in situ NPD cell designs and discuss methods for the analysis of the corresponding in situ NPD data produced using this cell.

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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2013

Lithium ion batteries employ flammable and volatile organic electrolytes that are suitable for ambient temperature applications. A safer alternative to organic electrolytes are solid polymer batteries. Solid polymer batteries operate safely at high temperatures (>120 °C), thus making them applicable to high temperature applications such as deep oil drilling and hybrid electric vehicles. This paper will discuss (a) the polymer synthesis, (b) the polymer conduction mechanism, and (c) provide...

Non-aqueous Electrode Processing and Construction of Lithium-ion Coin Cells

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Cited by 11 •

2016

Non-aqueous electrode processing is central to the construction of coin cells and the evaluation of new electrode chemistries for lithium-ion batteries. A step-by-step guide to the basic practices needed as an electrochemical engineer working with batteries in an academic experimental setting is furnished.

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