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DOI: 10.3791/50383-v
This study focuses on the synthesis of individual hydrophilic graphitic nanocups and their functionalization with gold nanoparticles. Techniques such as chemical vapor deposition and acid oxidation are employed to isolate the nanocups, which are then corked with gold nanoparticles.
We discussed the synthesis of individual graphitic nanocups using a series of techniques including chemical vapor deposition, acid oxidation and probe-tip sonication. By citrate reduction of HAuCl4, the graphitic nanocups were effectively corked with gold nanoparticles due to the chemically reactive edges of the cups.
The overall goal of the following experiment is to synthesize individual hydrophilic graphitic nano cups isolated from nitrogen, dumped carbon nano tubes, and functionalize them with gold nanoparticles as cork stoppers. This is achieved first by chemical vapor deposition to synthesize nitrogen doped carbon nanotubes consisting of stacked nano cups. As a second step, the stacked nano cups are treated with strong acid oxidation and probe tips on occasion, which effectively isolates the individual nano cups out of their stacks.
Next gold nanoparticles are synthesized by sodium citrate reduction of chloro oric acid in the presence of isolated nano cups in order to cork the nano cups at their opening results are obtained that show gold nanoparticles effectively corking the opening of the nano cups based on transmission electron microscopy and UV vis spectroscopy characterization. We first had the idea of separating and corking the carbon tube cups when we analyzed the transmission electron microscope images of nitrogen dope carbon tubes, and noticed that they're comprised of individual cup shaped segments. This method can help answer key questions in the nanoscience and nanotechnology field such as and properties of nanostructures with control, shape, and functionalities.
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