-1::1
Simple Hit Counter
Skip to content

Products

Solutions

×
×
Sign In

EN

EN - EnglishCN - 简体中文DE - DeutschES - EspañolKR - 한국어IT - ItalianoFR - FrançaisPT - Português do BrasilPL - PolskiHE - עִבְרִיתRU - РусскийJA - 日本語TR - TürkçeAR - العربية
Sign In Start Free Trial

RESEARCH

JoVE Journal

Peer reviewed scientific video journal

Behavior
Biochemistry
Bioengineering
Biology
Cancer Research
Chemistry
Developmental Biology
View All
JoVE Encyclopedia of Experiments

Video encyclopedia of advanced research methods

Biological Techniques
Biology
Cancer Research
Immunology
Neuroscience
Microbiology
JoVE Visualize

Visualizing science through experiment videos

EDUCATION

JoVE Core

Video textbooks for undergraduate courses

Analytical Chemistry
Anatomy and Physiology
Biology
Calculus
Cell Biology
Chemistry
Civil Engineering
Electrical Engineering
View All
JoVE Science Education

Visual demonstrations of key scientific experiments

Advanced Biology
Basic Biology
Chemistry
View All
JoVE Lab Manual

Videos of experiments for undergraduate lab courses

Biology
Chemistry

BUSINESS

JoVE Business

Video textbooks for business education

Accounting
Finance
Macroeconomics
Marketing
Microeconomics

OTHERS

JoVE Quiz

Interactive video based quizzes for formative assessments

Authors

Teaching Faculty

Librarians

K12 Schools

Biopharma

Products

RESEARCH

JoVE Journal

Peer reviewed scientific video journal

JoVE Encyclopedia of Experiments

Video encyclopedia of advanced research methods

JoVE Visualize

Visualizing science through experiment videos

EDUCATION

JoVE Core

Video textbooks for undergraduates

JoVE Science Education

Visual demonstrations of key scientific experiments

JoVE Lab Manual

Videos of experiments for undergraduate lab courses

BUSINESS

JoVE Business

Video textbooks for business education

OTHERS

JoVE Quiz

Interactive video based quizzes for formative assessments

Solutions

Authors
Teaching Faculty
Librarians
K12 Schools
Biopharma

Language

English

EN

English

CN

简体中文

DE

Deutsch

ES

Español

KR

한국어

IT

Italiano

FR

Français

PT

Português do Brasil

PL

Polski

HE

עִבְרִית

RU

Русский

JA

日本語

TR

Türkçe

AR

العربية

    Menu

    JoVE Journal

    Behavior

    Biochemistry

    Bioengineering

    Biology

    Cancer Research

    Chemistry

    Developmental Biology

    Engineering

    Environment

    Genetics

    Immunology and Infection

    Medicine

    Neuroscience

    Menu

    JoVE Encyclopedia of Experiments

    Biological Techniques

    Biology

    Cancer Research

    Immunology

    Neuroscience

    Microbiology

    Menu

    JoVE Core

    Analytical Chemistry

    Anatomy and Physiology

    Biology

    Calculus

    Cell Biology

    Chemistry

    Civil Engineering

    Electrical Engineering

    Introduction to Psychology

    Mechanical Engineering

    Medical-Surgical Nursing

    View All

    Menu

    JoVE Science Education

    Advanced Biology

    Basic Biology

    Chemistry

    Clinical Skills

    Engineering

    Environmental Sciences

    Physics

    Psychology

    View All

    Menu

    JoVE Lab Manual

    Biology

    Chemistry

    Menu

    JoVE Business

    Accounting

    Finance

    Macroeconomics

    Marketing

    Microeconomics

Start Free Trial
Loading...
Home
JoVE Journal
Engineering
Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as...
Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as...
JoVE Journal
Engineering
A subscription to JoVE is required to view this content.  Sign in or start your free trial.
JoVE Journal Engineering
Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as Cork Stoppers

Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as Cork Stoppers

Full Text
23,501 Views
11:58 min
May 13, 2013

DOI: 10.3791/50383-v

Yong Zhao1, Yifan Tang1, Alexander Star1

1Department of Chemistry,University of Pittsburgh

Overview

This study focuses on the synthesis of individual hydrophilic graphitic nanocups and their functionalization with gold nanoparticles. Techniques such as chemical vapor deposition and acid oxidation are employed to isolate the nanocups, which are then corked with gold nanoparticles.

Key Study Components

Area of Science

  • Nanotechnology
  • Materials Science
  • Nanostructures

Background

  • Graphitic nanocups are promising materials in nanoscience.
  • Understanding their properties can lead to advancements in nanotechnology.
  • Gold nanoparticles can enhance the functionality of nanostructures.
  • Isolation of individual nanocups is crucial for their application.

Purpose of Study

  • To synthesize individual graphitic nanocups from nitrogen-doped carbon nanotubes.
  • To functionalize these nanocups with gold nanoparticles.
  • To explore the properties and functionalities of the resulting nanostructures.

Methods Used

  • Chemical vapor deposition for synthesizing nitrogen-doped carbon nanotubes.
  • Acid oxidation and probe-tip sonication for isolating individual nanocups.
  • Sodium citrate reduction of HAuCl4 for synthesizing gold nanoparticles.
  • Characterization using transmission electron microscopy and UV-Vis spectroscopy.

Main Results

  • Successful isolation of individual graphitic nanocups.
  • Gold nanoparticles effectively cork the openings of the nanocups.
  • Characterization confirms the successful functionalization.
  • Insights into the properties of nanostructures are gained.

Conclusions

  • The method provides a pathway for controlling the shape and functionality of nanostructures.
  • Findings contribute to the understanding of nanoscience.
  • Potential applications in various fields of nanotechnology are suggested.

Frequently Asked Questions

What are graphitic nanocups?
Graphitic nanocups are nanoscale structures formed from carbon materials, shaped like cups, which have unique properties useful in various applications.
How are gold nanoparticles synthesized in this study?
Gold nanoparticles are synthesized using sodium citrate reduction of HAuCl4 in the presence of isolated nanocups.
What techniques are used to isolate the nanocups?
Techniques include acid oxidation and probe-tip sonication to effectively isolate individual nanocups from stacked structures.
What characterization methods are employed?
Transmission electron microscopy and UV-Vis spectroscopy are used to characterize the nanocups and confirm the presence of gold nanoparticles.
What is the significance of corking the nanocups?
Corking the nanocups with gold nanoparticles enhances their functionality and opens up new possibilities for their application in nanotechnology.

We discussed the synthesis of individual graphitic nanocups using a series of techniques including chemical vapor deposition, acid oxidation and probe-tip sonication. By citrate reduction of HAuCl4, the graphitic nanocups were effectively corked with gold nanoparticles due to the chemically reactive edges of the cups.

The overall goal of the following experiment is to synthesize individual hydrophilic graphitic nano cups isolated from nitrogen, dumped carbon nano tubes, and functionalize them with gold nanoparticles as cork stoppers. This is achieved first by chemical vapor deposition to synthesize nitrogen doped carbon nanotubes consisting of stacked nano cups. As a second step, the stacked nano cups are treated with strong acid oxidation and probe tips on occasion, which effectively isolates the individual nano cups out of their stacks.

Next gold nanoparticles are synthesized by sodium citrate reduction of chloro oric acid in the presence of isolated nano cups in order to cork the nano cups at their opening results are obtained that show gold nanoparticles effectively corking the opening of the nano cups based on transmission electron microscopy and UV vis spectroscopy characterization. We first had the idea of separating and corking the carbon tube cups when we analyzed the transmission electron microscope images of nitrogen dope carbon tubes, and noticed that they're comprised of individual cup shaped segments. This method can help answer key questions in the nanoscience and nanotechnology field such as and properties of nanostructures with control, shape, and functionalities.

View the full transcript and gain access to thousands of scientific videos

View the full transcript and gain access to thousands of scientific videos

Sign In Start Free Trial

Explore More Videos

Nitrogen-doped Carbon Nanotube CupsNCNCsChemical Vapor DepositionCVDGraphitic NanocupsOxidationAcid TreatmentProbe-tip SonicationSurface FunctionalitiesGold NanoparticlesGNPsNanoscale ContainersDrug Carriers

Related Videos

Template Directed Synthesis of Plasmonic Gold Nanotubes with Tunable IR Absorbance

13:37

Template Directed Synthesis of Plasmonic Gold Nanotubes with Tunable IR Absorbance

Related Videos

16.7K Views

Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica

11:02

Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica

Related Videos

10.6K Views

Synthesis, Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles

08:19

Synthesis, Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles

Related Videos

19K Views

In Situ Synthesis of Gold Nanoparticles without Aggregation in the Interlayer Space of Layered Titanate Transparent Films

07:08

In Situ Synthesis of Gold Nanoparticles without Aggregation in the Interlayer Space of Layered Titanate Transparent Films

Related Videos

8.6K Views

Fabrication of Periodic Gold Nanocup Arrays Using Colloidal Lithography

08:21

Fabrication of Periodic Gold Nanocup Arrays Using Colloidal Lithography

Related Videos

7.6K Views

Synthesis of Functionalized 10-nm Polymer-coated Gold Particles for Endothelium Targeting and Drug Delivery

10:38

Synthesis of Functionalized 10-nm Polymer-coated Gold Particles for Endothelium Targeting and Drug Delivery

Related Videos

13.2K Views

Synthesis of Substrate-Bound Au Nanowires Via an Active Surface Growth Mechanism

09:36

Synthesis of Substrate-Bound Au Nanowires Via an Active Surface Growth Mechanism

Related Videos

8.4K Views

Growth of Gold Dendritic Nanoforests on Titanium Nitride-coated Silicon Substrates

05:02

Growth of Gold Dendritic Nanoforests on Titanium Nitride-coated Silicon Substrates

Related Videos

7K Views

Microscopic Visualization of Porous Nanographenes Synthesized through a Combination of Solution and On-Surface Chemistry

08:18

Microscopic Visualization of Porous Nanographenes Synthesized through a Combination of Solution and On-Surface Chemistry

Related Videos

2.2K Views

Gold Nanoparticle Synthesis

13:42

Gold Nanoparticle Synthesis

Related Videos

16.1K Views

JoVE logo
Contact Us Recommend to Library
Research
  • JoVE Journal
  • JoVE Encyclopedia of Experiments
  • JoVE Visualize
Business
  • JoVE Business
Education
  • JoVE Core
  • JoVE Science Education
  • JoVE Lab Manual
  • JoVE Quizzes
Solutions
  • Authors
  • Teaching Faculty
  • Librarians
  • K12 Schools
  • Biopharma
About JoVE
  • Overview
  • Leadership
Others
  • JoVE Newsletters
  • JoVE Help Center
  • Blogs
  • JoVE Newsroom
  • Site Maps
Contact Us Recommend to Library
JoVE logo

Copyright © 2026 MyJoVE Corporation. All rights reserved

Privacy Terms of Use Policies
WeChat QR code