Journal
/
Chemistry
/
Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in Poly(S-Divinylbenzene)
JoVE Journal
Chemistry
A subscription to JoVE is required to view this content.  Sign in or start your free trial.
JoVE Journal Chemistry
Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in Poly(S-Divinylbenzene)

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in Poly(S-Divinylbenzene)

DOI:
10.3791/59620-v

•

09:16 min

•

May 20, 2019

•

, ,
1Department of Chemistry,Ball State University

Chapters

  • 00:04Title
  • 01:06Synthesis of Poly(S-divinylbenzene)
  • 01:53Preparation of Terpolymers
  • 04:11Control Polymerizations, Polymer Characterization, and Solubility Studies
  • 06:41Results: Polysulfide Initiated Polymerization and Characterization of Terpolymers
  • 08:32Conclusion

Summary

Automatic Translation

Automatic Translation

The goal of this protocol is to initiate polymerization using dynamic sulfur bonds in poly(S-divinylbenzene) at mild temperatures (90 °C) without using solvents. Terpolymers are characterized by GPC, DSC and 1H NMR, and tested for changes in solubility.

Tags

Keywords: PolysulfideInverse VulcanizationTerpolymerDynamic Sulfur BondsPoly(S-divinylbenzene)14-Cyclohexanedimethanol Divinyl EtherMaleimideMild Temperature Polymerization

Article

Embed

ADD TO PLAYLIST

Usage Statistics

Related Videos

check_url/59620?article_type=v

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
check_url/59620?article_type=v

Synthesis of Immunotargeted Magneto-plasmonic Nanoclusters
check_url/59620?article_type=v

Synthesis, Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles
check_url/59620?article_type=v

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
check_url/59620?article_type=v

Synthesis of Ligand-free CdS Nanoparticles within a Sulfur Copolymer Matrix
check_url/59620?article_type=v

Synthesis of Protein Bioconjugates via Cysteine-maleimide Chemistry
check_url/59620?article_type=v

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
check_url/59620?article_type=v

Synthesis of a Water-soluble Metal–Organic Complex Array
check_url/59620?article_type=v

DNA-magnetic Particle Binding Analysis by Dynamic and Electrophoretic Light Scattering
check_url/59620?article_type=v

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Read Article