Electrode Potential

Electrode potential is the voltage developed between an electrode and the surrounding electrolyte, reflecting the electrode’s tendency to gain or lose electrons. It arises from interfacial redox reactions: when an electrode contacts a solution containing its ions, charge separation establishes an equilibrium potential that depends on the chemical composition, temperature, and concentrations involved, as described by the Nernst equation. Measuring electrode potentials enables chemists to predict cell voltage, reaction direction, and spontaneity in electrochemical systems. These principles support the design of batteries and fuel cells, analysis with reference electrodes, electroplating, corrosion studies, and control of industrial redox processes.

Electrode Potential - Related Videos

Education

JoVE Core - Chemistry

Standard Electrode Potentials

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2020

On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...

Research

JoVE EoE - Neurophysiology

Recording of Visual Evoked Potentials via the Skull Electrodes in a Rat Model

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2025

This video demonstrates the process of measuring visual evoked potentials or VEPs in a dark-adapted, anesthetized rat with pre-implanted skull electrodes, which record the electrical signals from the brain's visual cortex in response to light stimuli.

Fabrication of Amperometric Electrodes

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Cited by 8 •

2009

This protocol describes how to generate carbon fiber electrodes. The electrodes are subsequently used to detect catecholamine release from vesicles with carbon fiber amperometry.

Implanting an Electrode into the Subthalamic Nucleus of a Rat

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2025

The video demonstrates a procedure for implanting an electrode into the subthalamic nucleus of a rat to deliver electrical stimuli.

Education

JoVE Science Education - Physics
Free Sample

Electric Potential

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2023

Source: Yong P. Chen, PhD, Department of Physics & Astronomy, College of Science, Purdue University, West Lafayette, IN Electric potential, also known as "voltage", measures the electric potential energy per unit charge. Electric field is a scalar quantity and is fundamental to many electrical effects. Like potential energy, what is physically meaningful is the difference in the electric potential. For example, the spatial variation in the electric potential is related to the electric...

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