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Udforskning den radikale karakter af et Carbon overflade ved Electron Paramagnetisk Resonans og en kalibreret Gas Flow

Article DOI: 10.3791/51548-v • 10:34 min • April 24th, 2014
April 24th, 2014 •
1,2, 3, 1, 2,4, 3
1Chemistry Institute, The Hebrew University of Jerusalem, 2Biological Chemistry Department, Ariel University, 3Chemistry Department, Faculty of Exact Science, Bar Ilan University, 4Chemistry Department, Ben-Gurion University

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Stabile radikaler, der er til stede i carbonsubstrater interagere med paramagnetisk oxygen gennem en Heisenberg spinudveksling. Denne interaktion kan reduceres betydeligt under STP forhold ved at strømme en diamagnetisk gas over kulstof-systemet. Dette håndskrift beskriver en simpel metode til at karakterisere arten af ​​disse radikaler.

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Kemi Carbon-centreret radikal elektron paramagnetisk resonans (EPR) oxidation radikaler ilt kulstof
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