Atomic Oxygen Oxidation

Atomic oxygen oxidation is a chemical process in which highly reactive, isolated oxygen atoms convert molecules or materials into oxidized products. Because atomic oxygen has an unpaired electron, it readily abstracts hydrogen, adds to chemical bonds, and promotes bond cleavage, often generating reactive oxygen-containing intermediates before forming stable oxides, carbonyls, or other oxygenated compounds. In chemistry, this process helps explain oxidation under plasma, photochemical, combustion, and upper-atmosphere conditions. It is also used to modify polymer and carbon surfaces, remove organic contaminants, study material degradation in low Earth orbit, and control surface chemistry for adhesion, catalysis, and advanced materials research.

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Education

JoVE Core - Chemistry

Oxidation Numbers

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2020

In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the oxidation number (or oxidation state). It represents the effective charge of an atom or element, which is assigned using a set of rules. Oxidation Number (Oxidation State) In the case of an ionic compound, oxidation numbers are assigned based on the number of electrons transferred between reacting species. For example, in the formation of calcium...

Research

JoVE Journal - Chemistry
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U2O5 Film Preparation via UO2 Deposition by Direct Current Sputtering and Successive Oxidation and Reduction with Atomic Oxygen and Atomic Hydrogen

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Cited by 1 •

2019

This protocol presents the preparation of U2O5 thin films obtained in situ under ultra-high vacuum. The process involves oxidation and reduction of UO2 films with atomic oxygen and atomic hydrogen, respectively.

Detecting Reactive Oxygen Species

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2023

Reactive oxygen species are chemically active, oxygen-derived molecules capable of oxidizing other molecules. Because of their reactive nature, there are many deleterious effects associated with unchecked ROS production, including structural damage to DNA and other biological molecules. However, ROS can also be mediators of physiological signaling. There is accumulating evidence that ROS play significant roles in everything from activation of transcription factors to the mediation of...

The Atomic Theory of Matter

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2020

The earliest recorded discussion of the basic structure of matter comes from ancient Greek philosophers. Leucippus and Democritus argued that all matter was composed of small, finite particles that they called atomos, meaning “indivisible.” Later, Aristotle and others came to the conclusion that matter consisted of various combinations of the four “elements” — fire, earth, air, and water — and could be infinitely divided. Interestingly, these philosophers thought about atoms and “elements” as...

Atomically Traceable Nanostructure Fabrication

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Cited by 4 •

2015

We report a protocol for combining the atomic metrology of the Scanning Tunneling Microscope for surface patterning with selective Atomic Layer Deposition and Reactive Ion Etching. Using a robust process involving numerous atmospheric exposures and transport, 3D nanostructures with atomic metrology are fabricated.

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