Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

G&#252;nther Thiele; Carsten Donsbach; Isabell Nu&#223;bruch; Stefanie Dehnen

doi:10.3791/54789

Journal

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화학

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고체 및 솔루션 기반의 기술 결합 : 합성 및 Chalcogenidoplumbates의 반응성 (II 또는 IV)

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

고체 및 솔루션 기반의 기술 결합 : 합성 및 Chalcogenidoplumbates의 반응성 (II 또는 IV)

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10,660 Views

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10:42 min

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December 29, 2016

DOI:

10.3791/54789-v

DOI:

10.3791/54789-v

•

10:42 min

December 29, 2016

•

10645 Views

Günther Thiele¹, Carsten Donsbach², Isabell Nußbruch², Stefanie Dehnen²

¹Department of Chemistry,University of California, Berkeley ²Fachbereich Chemie,Philipps-Universität Marburg and Wissenschaftliches Zentrum für Materialwissenschaften

Summary

The synthesis of chalcogenidoplumbates(II,IV) via the in situ reduction of nominal "PbCh₂" (Ch = Chalcogen) and via a solid-state reaction and subsequent solvothermal reactions is presented. Additionally, reactivities of plumbate(II) solutions are portrayed, which yield the heaviest-known CO homolog known to date: the µ-PbSe ligand.