Name: flame test metal color clues
Uploaded: 2020-03-26T07:22:25.000Z
Duration: 2 min 47 s
Channel: JoVE

K12 Standards

Texas Essential Knowledge and Skills

High School

Chemistry and Physics

IPC.7

IPC.7.E

Metal Flame Emission

Flame testing is an analytical technique where a sample is applied to a flame, and the characteristic emission spectrum is used to identify different elements. When this technique is used to identify metal species, it is called metal flame emission testing. When sufficient energy is applied to some metals through a hot flame, they emit light with a characteristic wavelength or color. You can clearly see this phenomenon when watching a fireworks display.
Different metals emit different colors. Thus, we can use the color of the emitted light to determine the metal present. But before we dive into the technique further, let&#39;s take a step back. Atoms have multiple energy levels for their electrons, which are different for each element.
When an electron is at its lowest possible energy level, it is said to be at its ground state. When an atom absorbs energy, it gets excited, and electrons in the atom move from the ground state to a higher energy level. When the electrons relax back down to a lower state, or the ground state, the excess energy gained is released in the form of emitted light.
The wavelength of the emitted light depends on the energy level that the electron was excited to and the level that it relaxes back to. This emitted wavelength, or color of light, is specific to the atom present and is used to identify a metal sample in the metal flame emission test.
In the metal flame emission test, we apply a metal sample to a hot flame and observe the color of the emitted light. For example, barium will emit a yellowish-green color in the flame, while copper emits blue-green and potassium a pinkish-purple.
Now, a sample actually consists of the metal, metal ions, metal oxides, metal hydroxides, and metal salts. And since atoms and molecules absorb and release energy differently, the emitted light actually contains a range of wavelengths and intensities forming an emission spectrum.
A spectrophotometer is used to measure the range of wavelengths of emitted light.&#160;
In this lab, you&#39;ll use the metal flame emission test to identify various metals and then analyze the emitted and absorbed light using a spectrophotometer.

metal flame emission

<h4>Metal Flame Emission</h4>
Flame testing is an analytical technique where a sample is placed in a flame, and the characteristic flame color is used to identify the substance. Each element has a characteristic light emission when placed into a flame, meaning each element produces a unique color. This phenomenon is used in fireworks displays, where the color of the fireworks corresponds to a specific characteristic of a metal. The emission of colored light from a burning sample is the direct result of the metallic component absorbing energy due to the excitation from the flame and emitting light as a result.
<h4>Electron Excitement</h4>
When an atomic or molecular species absorbs energy, the energy is used in four different ways. First, the energy is used in translation, causing the molecules to move faster. Second, the energy is used in vibration, which causes the distance between the species to change rapidly. Third, the energy causes rotation, which induces the rotation of atoms around the bonds in the molecule. Finally, the absorbed energy results in electron excitement, which causes electrons to move to a higher energy level from the most stable or ground state.
According to the Bohr model of hydrogen, electrons in an atom exist in discrete states, which correspond to individual shells or orbitals around the nucleus. The lowest energy state is called the ground state and is represented by the notation of n = 1. Excited energy states have higher energies and are represented by the notation of n = 2, 3, 4, etc.
For electrons to move to a higher energy state, they must absorb an amount of energy that is equal to the difference between its ground state and the higher energy state. For example, if an electron absorbs an amount of energy that is equal to the difference between the ground state and the n=3 energy level, the electron will move to the n=3 energy level. An electron can spontaneously relax back down to the ground state or any other lower energy level. When this occurs, a photon is emitted, releasing the absorbed energy.
The released energy is emitted in the form of light. The emitted light has a characteristic energy, and therefore, wavelength, that correlates to the energy levels of the atom. Visible light, which is the light humans can see with their eyes, ranges from about 400 nm to 700 nm on the electromagnetic spectrum.
Atomic absorptions and emissions are discrete wavelengths, called lines. These lines are unique characteristics of an element, like a barcode, and can be used to identify the element.
<h4>Metal Flame Emission Test</h4>
In the metal flame emission test, a metal sample is placed in a flame. The flame provides the energy to excite electrons to a higher energy level. As the electrons relax back down to the ground state, light is emitted with a specific energy relative to the energy levels of the atoms in the sample. Since different atoms have different energy levels, the energy absorbed and emitted from a sample, and thus the wavelength, is specific to the sample.
Metals have characteristic atomic emission wavelengths in the visible range that are easily determined by visual inspection. For example, lithium emits a red color, sodium emits a yellow color, potassium emits a pink-purple color, and barium emits a yellow-green color.
While atomic emissions are discrete wavelengths or lines, most samples of metals contain not only the metal, but also various metal ions, oxides, and salts. Since each atom absorbs and emits a characteristic wavelength of light, the absorbed and emitted light from the flame test contains a range of wavelengths. Thus, atomic absorption and emission spectra can be measured for the sample using a spectrophotometer.
The wavelengths and shapes of the spectra are unique for each substance. For example, the relative intensity of features in the spectrum depends on the concentration of the species. The absolute intensities are dependent on the distance from the sample to the spectrophotometer.
<h4>References</h4>
<ol>
	<li style="font-size:17px">Kotz, J.C., Treichel Jr, P.M., Townsend, J.R. (2012). Chemistry and Chemical Reactivity. Belmont, CA: Brooks/Cole, Cengage Learning.</li>
	<li style="font-size:17px">Silderberg, M.S. (2009). Chemistry: The Molecular Nature of Matter and Change. Boston, MA: McGraw Hill.</li>
	<li style="font-size:17px">Harris, D.C. (2015). Quantitative Chemical Analysis. New York, NY: W.H. Freeman and Company.</li>
</ol>

Metal Flame Emission
Flame testing is an analytical technique where a sample is placed in a flame, and the characteristic flame color is used to identify ...

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flame test metal color clues

Flame testing uses a metal sample and a flame to identify a substance by its color. Each element gives off a characteristic light emission in the flame, so the color can help distinguish one element from another. This same idea appears in fireworks, where different metal components create different colors.

The color comes from energy absorbed by the metallic component. When a species absorbs energy, that energy can go into translation, vibration, rotation, or electron excitement. Electron excitement is the key step in flame emission because it moves electrons from the ground state, the lowest energy state, to a higher energy level.

In the Bohr model of hydrogen, these energy states are separate, or discrete. The ground state is written as n = 1, and higher states are written as n = 2, 3, 4, and so on. An electron moves up only if it absorbs the exact energy difference between its current level and the higher one.

The electron can then relax back to the ground state or another lower level. When that happens, a photon is released as light. The emitted light has a specific energy and wavelength, and visible light ranges from about 400 nm to 700 nm. These atomic absorption and emission wavelengths are discrete lines, and they act like a barcode for identifying an element.

In a metal flame emission test, the flame supplies the energy that excites the electrons. As the electrons fall back down, the sample gives off light with a wavelength tied to its atomic energy levels. Because different atoms have different energy levels, the emitted wavelength is specific to the sample.

Many metals show visible colors that are easy to spot by eye. Lithium gives a red color, sodium gives yellow, potassium gives pink-purple, and barium gives yellow-green. Real samples often contain metal ions, oxides, and salts as well as the metal itself, so the light from the flame test can include a range of wavelengths.

That range can also be measured with a spectrophotometer as atomic absorption and emission spectra. The shapes and wavelengths of the spectra are unique for each substance. The relative intensity of spectral features depends on concentration, while the absolute intensity depends on the distance from the sample to the spectrophotometer.

Flame Test Metal Color Clues

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Flame Test Metal Color Clues

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