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Heterogene Entfernung von wasserlöslichen Ruthenium Olefin-Metathese-Katalysator von wässrigen Medien über Wirt-Gast-Interaktion
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Heterogene Entfernung von wasserlöslichen Ruthenium Olefin-Metathese-Katalysator von wässrigen Medien über Wirt-Gast-Interaktion

Article DOI: 10.3791/58067-v • 10:39 min • August 23rd, 2018
August 23rd, 2018 •
1, 1
1Department of Chemical and Biomedical Engineering, Florida State University

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Eine abnehmbare wasserlösliche N-heterozyklische Carben (NHC) Liganden in wässrigen Medien über Wirt-Gast-Interaktion entwickelt wurde. Wir zeigen repräsentative Olefin Metathese-Reaktionen im Wasser so gut wie in Dichlormethan. Entweder über Wirt-Gast-Interaktion oder Extraktion war der Rest Ruthenium (Ru) Katalysator nach der Reaktion so niedrig wie 0,14 ppm.

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Chemie Ausgabe 138 Wirt-Gast-Interaktion wasserlöslich homogene Katalyse heterogene entfernen Katalysator entfernen Metathese
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