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Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization

Article DOI: 10.3791/53212-v • 07:28 min • November 27th, 2015
November 27th, 2015 •
1, 1
1Department of Chemistry, University of Minnesota - Twin Cities

Kapitel

Summary
Automatic Translation

A protocol for the high-throughput analysis of polymerization catalyst, chain transfer polymerizations, polyethylene characterization, and reaction kinetic analysis is presented.

Tags

High-throughput Catalyst Screening Parallel Pressure Reactor Nickel &945;-diimine Ethylene Polymerization Catalyst Reaction Conditions Catalyst Concentration Ethylene Pressure Reaction Time Gas-uptake Data Initial Rate Of Propagation (kp) Nickel &945;-diimine Polymerization Catalyst Chain Transfer Diethylzinc (ZnEt2) Molecular Weight 13C NMR Data Degree Of Chain Transfer Chain Transfer Rates (ke)
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