- 00:07Overview
- 01:19Principles of Extrusion
- 02:59Extruder Start-up and Heat-soak
- 04:21Extruder Operation and Data Collection
- 05:43Extruder Shut Down and Data Processing
- 06:48Results
- 07:53Applications
- 09:41Summary
Demonstração do modelo de lei de potência por meio de extrusão
English
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Overview
Fonte: Kerry M. Dooley e Michael G. Benton, Departamento de Engenharia Química, Louisiana State University, Baton Rouge, LA
Os derretimentos de polímeros são frequentemente formados em formas simples ou “extrudatas”, como pelotas cilíndricas, folhas planas ou tubos, usando uma extrusora. 1 Os poliolefinas estão entre os polímeros extrudáveis mais comuns. A extrusão envolve o transporte e o derretimento da alimentação sólida, que às vezes é misturado com materiais não poliméricos, e o acúmulo de pressão e transporte do derretimento ou mistura. É aplicado a polímeros termoplásticos, que se deformam quando aquecidos e retomam suas propriedades anteriores de “sem fluxo” quando resfriados.
Utilizando uma simples extrusora de laboratório, o efeito das condições de operação na saída de polímero e na queda de pressão pode ser examinado e os dados resultantes podem ser correlacionados usando o modelo “Power Law” para o fluxo de derretimentos e soluções de polímeros. Este modelo é usado para escalar o processo para extrusoras mais complexas. A relação entre as condições de funcionamento e os desvios do comportamento de deslocamento teórico (“deslizamento”) e a forma extrudata (“die swell”) pode ser determinada.
Neste experimento, será utilizado um polímero termoplástico típico, como um copolímero de polietileno de alta densidade (HDPE) (de etileno + uma olefina de cadeia mais longa). A temperatura de operação para o dado e zonas dependem do material. A taxa de fluxo pode ser determinada pesando a saída de dado em intervalos cronometrado. Todos os outros dados necessários (velocidade do parafuso, temperaturas da zona, pressão entrando no dado) podem ser lidos no painel de instrumentos.
Principles
Procedure
Results
The Q vs. ΔP relationship was calculated using the Power Law model, and ir takes on a simple form for flow in a conduit of simple geometry, which in this case is the die. From the flow, speed, and temperature measurements, the Power Law constants and other quantities, such as shear rate, shear stress, and degree of slippage were calculated. Representative data and a fit to Equation 2 by linear regression are shown in Figure 2. The data spanned the following ranges: mass flow = 11 – 28 g/min, shear rate (at wall) = 35 – 85 s-1, viscosity (at wall) = 760 – 460 Pa·s.
Figure 2: Results depicting the relationship between pressure (P) and flow rate (Q).
The linear regression fit was good (R2 = 0.9996). However, in order to apply linear regression to Equation 2 the log ratio of Q to Q0 (Q0 can be any data point, but the lowest Q was used here) was regressed, which lost a degree of freedom. This is not the case for nonlinear regression, which indicates that nonlinear regression should give a better fit. The Power Law index and modulus of viscosity were calculated from the data shown. The power law index (n) was determined to be 0.42 and the modulus of viscosity (m) was determined to be 2.2 x 10-2 MPa*sn.
Flow rate appeared to have some slight effect on the die swell ratio. However, increasing the flow rate had no effect on polymer slippage, at least for the data in Figure 3.
Figure 3: Relationship between volumetric flow rate (Q) and speed in RPM.
Applications and Summary
Polymer extrusion begins by melting polymer resins that enter the extruder through the hopper. The flow of the molten polymer depends on the viscosity (ratio of shear stress to shear rate) behavior of the substance. The polymer leaves through the die, and is shaped to desired dimensions. The flow of polymer is expected to follow the Power Law model.
In this experiment, the mechanics of the Power Law model, including how it is used in conjunction with the z-direction equation of motion to analyze the flow of a non-Newtonian fluid, and how greatly the flows and viscosities change in response to screw speed and T were observed. Viscoelastic fluids have a Power Law index <1 whereas for Newtonian fluids, the index is 1. This indicates that as the speed increases, the viscosity decreases and less power/mass is required for the melt to flow.
Extrusion is a primary process for creating many types of pipes and tubing, films, wire insulation, coatings, and other plastic products.1 Extrudable products include polyvinyl chloride (PVC), commonly used for piping, polyethylene and its copolymers, which often used for packaging, polypropylene, ABS, acetals, and acrylics.1
Extrusion is an efficient process for converting polymers into simple shapes. However, many extruders also function to mix non-polymeric materials with polymers. The helical flow through the flights promotes efficient mixing. Such non-polymeric additives include plasticizers (organic compounds used to lower the viscosity and make the product more ductile), antioxidants, and flame retardants. Even inorganic fillers such as carbons, clays and talc can be added, within limits (because they don't melt). Fillers modify the mechanical properties of the final product, often imparting more toughness.
Other extrusion processes, such as blown film extrusion and over-jacketing extrusion, can create unique products, but they are more specialized for a limited range of products. A key use for extruders is to feed the products to either blow or injection molders. Injection molding makes a wide variety of complex products ranging from car body and under-hood parts to toys to gears. Over-jacketing extrusion is used to coat electrical wires, while tubing extrusion (annular die) creates industrial and residential piping. Plastic sheets are created by flow through a die that looks similar to a coat hanger.1
Extruders are also frequently used in food processing. Products such as pasta, bread, and cereals are extruded in mass quantities. Starches are most commonly processed in food extrusion due to their moisture content and viscosity profile. The process of melting in plastic extrusion becomes the process of cooking in food production. Other food products created through extrusion are confectionaries, cookie doughs, and pet foods.
Materials List
| Name | Company | Catalog Number | Comments |
| Equipment | |||
| Single-Screw Extruder | SIESCOR | 3/4" diameter screw, L/D ratio = 20 | |
| LLDPE | Dow | LLD2 | Alternative polymer to BA50, melting temperature= 191 °C, s.g. = 0.930 |
| HDPE Copolymer | ExxonMobil | Paxon BA50 | Melting temperature= 204 °C, s.g. = 0.949 |
| ¼ HP DC Motor | MINARIK | Single reduction worm gear reducer, ratio 31:1 |
References
- Principles of Polymer Processing, Z. Tadmor and C.G. Gogos, Wiley Intersicence, Hoboken, 2006 (Ch. 3, 4, 6, 9-10); Analyzing and Troubleshooting Single Screw Extruders, G. Campbell and M.A. Spalding, Carl Hanser, Munich, 2013 (Ch. 1, 3, A3).
- Transport Phenomena by R.B. Bird, W.E. Stewart, and E.N. Lightfoot, John Wiley, New York, 1960 (Ch. 2-3) and Process Fluid Mechanics by M.M. Denn, Prentice-Hall, Englewood Cliffs, 1980 (Ch. 2, 8, 19)
Transcript
Extrusion is an industrial process that transforms polymers and other materials into defined shapes, such as tubing and pipes for applications as diverse as car parts and toys. It is studied at the small scale prior to the design of industrial machines. Common materials for extrusion are polyolefins, polyethylene, and copolymers. During extrusion, the thermal plastic material, known as solid feed, is transported, mixed, and melted. The substance is passed through a mold known as the die, after which it cools and resumes to the non-pliable properties. Simple lab extruders can be used to investigate various parameters affecting the polymer output using a power law model. Furthermore, relationships between operating conditions and deviations from theoretical behavior, as well as extrudate shape, can be established. This video will illustrate how an extruder works, how to operate it, and how to use the power law model to evaluate the process.
The extruder consists of a hopper, which feeds in the polymer granules, a barrel, composed of a cylindrical chamber with resistive heating elements to control the different temperature zones, and a helical screw that rotates around the center line. The channels of the screw are widest at the feeder to promote mixing and melting. However, the channels become increasingly narrow and shallow along the length of the screw. The screw is designed to ensure steady transport from the feeder, while accounting for the reduction in volume and build-up and pressure as the feed melts. The behavior of a molten polymer depends on the temperature, pressure, and the viscosity, which is the ratio of shear stress to shear rate. For most polymers, viscosity decreases with both temperature and shear rate, making them non-Newtonian fluids. Specifically, polymer melts are usually viscoelastic and their flow is described by a power law model. The power law contains two empirical constants. M is the modulus of viscosity and strongly temperature-dependent. And n may also vary with temperature. The power law constants can be calculated from the volumetric flow rate, pressure, and geometry. The flow rate is established by weighing the die output over two time intervals. Now that you know how an extruder works, let’s apply the power law model in a real experiment.
The thermoplastic material used in this experiment is a high density polyethylene copolymer, which contains links of both ethylene and a long chain olefin. To start, turn the exhaust to on. Take the polymer pellets and fill the hopper of the extruder. Ensure that the motor switch is off and then turn the main switch to on. The temperature settings should be adjusted to the material in use. Set the temperature of zone one to around five to 20 degrees Celsius above the melting point of the polymer, which is approximately 200 degrees Celsius. Set the temperature of zone three, which is the temperature of the cylindrical die, between 220 and 250 degrees Celsius. Finally, set the temperature of zone two to be between zones one and three. Check the temperature of all heated zones to see if they reached the desired set-point. Once set-points are reached, wait for a minimum of one hour, a phase called heat-soak. Heat-soak ensures melting of any residual solid polymer, which otherwise can exert excessively high pressure on the die, resulting in unsteady flows.
Turn the motor to on. Set the desired speed using the switch starting with low RPM. And gradually increase the speed as the polymer is seen exiting the die until the lowest desired speed is reached. Do not exceed 3,000 psi die pressure. Run the extruder for 10 minutes after the desired speed has been reached. Periodically check the hopper to ensure it has enough resin pellets. Pre-weigh the pans to be used for sample collection. Put on safety gloves. Using scissors, carefully cut the very hot extrudate into a pre-weighted pan and weigh the mass of polymer that was extruded between measured time intervals to calculate the flow rate. Measure the diameter of the extrudate ribbon with a micrometer. Using the speed controller, adjust the set-point to a new setting and wait for 10 minutes. Collect samples and data as performed previously. To obtain the data set at different temperatures, lower the speed and use the temperature controllers to adjust the set-point of the zones. Wait for 15 minutes before collecting the samples.
Turn off both the extruder motor switch and the main switch. Using the mass rate and the melt density of the polymer, calculate the volumetric flow rate, Q. Use the power law to determine the modulus of viscosity, m, and the power law index, n, that best characterize the material at a given die temperature. The linchpin between these two equations is the momentum balance, which relates shear stress to the pressure drop across the barrel. Combine these three equations into a differential equation that can be solved to yield volumetric flow rate. Linearize this equation and use both linear and nonlinear regression to find m and n and compare the results. Now, let’s analyze the data and examine how well it is fitted by the power law model and whether it is consistent with the model at all.
The linear regression to the power law model is seen in this graph, which depicts the relationship between the pressure, P, and the flow rate, Q. The coefficient of determination shows a good fit. The power law index, n, and modulus of viscosity, m, indicate that this is a pseudoplastic, that is, as shear rate increase, viscosity decreases. It is over 10 million times more viscous than water at room temperature, and 10,000 times more viscous than glycerin. The flow rate appeared to have some slight affect on the die swell ratio, but not on polymer slippage. In summary, it shows that the power law model, in conjunction with the momentum equation, suitably describe the flow of this non-Newtonian fluid, indicating the flow and viscosity changes in response to screw speed and temperature.
A variety of extrusion techniques exist that are used in both industrial skill processes and benchtop research to create various types of products, ranging from pipes and plastics to biomaterials. Extruders convert polymers into simple shapes. They can also mix non-polymeric additives to the polymer blend. Additives are added in order to modify the mechanical properties of the final product, often imparting more toughness. Examples include plasticizers, antioxidants, and flame retardants. Inorganic additives, such as talc or carbon, are of limited use because they do not melt. Extrusion is also the basis for 3D printing, a process in which a thermoplastic ink exits from a nozzle and is deposited on a surface in many layers to create a three-dimensional material. This versatile technique is being explored in bioengineering applications to bio-print tissue-specific cell constructs. Another key use for extruders is to feed products to an injection mold, which forces the material into a mold cavity using pressure. It is similar to die-casting. This process creates more specialized products and is therefore limited in its range of application. Besides piping, tubing, and packaging materials, extrusion is also commonly used for food processing. Products, such as bread, pasta, confectioneries, cereals, or pet foods, are extruded in mass quantities. Products high in starch content are commonly processed in food extrusion because of their moisture and viscosity profiles.
You’ve just watched JoVE’s introduction to polymer extrusion. You should now understand the process of extrusion, how the flow, speed, and temperature can affect the process, and how to apply the power law model to evaluate it. Thanks for watching.