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A Study of the Complexation of Mercury(II) with Dicysteinyl Tetrapeptides by Electrospray Ionization Mass Spectrometry
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A Study of the Complexation of Mercury(II) with Dicysteinyl Tetrapeptides by Electrospray Ionization Mass Spectrometry

Article DOI: 10.3791/53536-v • 12:59 min • January 8th, 2016
January 8th, 2016 •
1, 2
1Department of Chemistry and Biochemistry, University of North Carolina at Greensboro, 2Department of Chemistry, Winston-Salem State University

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The characterization of complexes formed in different relative ratios of mercury(II) to dicysteinyl tetrapeptides by electrospray ionization orbitrap mass spectrometry is presented.

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Complexation Mercury(II) Dicysteinyl Tetrapeptides Electrospray Ionization Mass Spectrometry Reaction Stoichiometries Characterize Complexes Chelating Agents Sequestering Mercury Ions Metal Ion Complexes Orbitrap Mass Spectrometry Fragmentation Mercury Isotopic Distribution Pattern Tandem Mass Spectrometry Ammonium Formate Buffer Argon Mercury Chloride Solution
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