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Method Article

An Available Technique for Preparation of New Cast MnCuNiFeZnAl Alloy with Superior Damping Capacity and High Service Temperature

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DOI:

10.3791/57180

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September 23rd, 2018

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In This Article

Summary

Here we present a protocol to obtain a novel Mn-Cu-based alloy with excellent comprehensive performances by a high-quality smelting technology and reasonable heat treatment methods.

Abstract

Manganese (Mn)-copper (Cu)-based alloys have been found to have damping capacity and can be used to reduce harmful vibrations and noise effectively. M2052 (Mn-20Cu-5Ni-2Fe, at%) is an important branch of Mn-Cu-based alloys, which possesses both excellent damping capacity and processability. In recent decades, lots of studies have been carried out on the performance optimization of M2052, improving the damping capacity, mechanical properties, corrosion resistance, and service temperature, etc. The major methods of performance optimization are alloying, heat treatment, pretreatment, and different ways of molding etc., among which alloying, as well as adopting a reasonable heat treatment, is the simplest and most effective method to obtain perfect and comprehensive performance. To obtain the M2052 alloy with excellent performance for casting molding, we propose to add Zn and Al to the MnCuNiFe alloy matrix and use a variety of heat treatment methods for a comparison in the microstructure, damping capacity, and service temperature. Thus, a new type of cast-aged Mn-22.68Cu-1.89Ni-1.99Fe-1.70Zn-6.16Al (at.%) alloy with superior damping capacity and high service temperature is obtained by an optimized heat treatment method. Compared with the forging technique, cast molding is simpler and more efficient, and the damping capacity of this as-cast alloy is excellent. Therefore, there is a suitable reason to think that it is a good choice for engineering applications.

Introduction

Since the Mn-Cu alloys were found by Zener to have damping capacity1, they have received widespread attention and research2. The advantages of Mn-Cu alloy are that it has high damping capacity, especially at low strain amplitudes, and its damping capacity cannot be disturbed by a magnetic field, which is quite different from ferromagnetic damping alloys. The high damping capacity of Mn-Cu-based alloys can be mainly attributed to the movability of the internal boundaries, mainly including twin boundaries and phase boundaries, which are generated in the face-centered-cubic-to-face-centered-tetragonal (f.c.c.-f.c.....

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Protocol

1. Preparation of the Raw Materials

  1. Weigh all the required raw materials with an electronic scale by mass percentage (65% electrolytic Mn, 26% electrolytic Cu, 2% industrial pure Fe, 2% electrolytic Ni, 3% electrolytic Al, and 2% electrolytic Zn), as shown in Figure 1.
    ​NOTE: All these raw materials were commercially available.

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Results

Figure 7 shows the dependency of the damping capacity on the strain amplitude for the as-cast MnCuNiFeZnAl alloy specimens #1 - #7 and as-cast M2052. The results show that the damping capacity of specimen #1 is higher than that of cast M2052 alloy (as shown in Figure 7a) and the traditional forged M2052 high-damping alloy mentioned in previous articles20,21. Moreover, the.......

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Discussion

To ensure that this kind of as-cast Mn-Cu-based alloy possesses both superior damping capacity and excellent mechanical properties, it is necessary to ensure that the castings have a stable chemical composition, a high purity, and an excellent crystal structure. Therefore, strict quality control is necessary for the smelting, pouring, and heat treatment processes.

Firstly, it is necessary to choose the proper ingredients for the alloy. It should be considered that the added alloy elements.......

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Disclosures

The authors have nothing to disclose.

Acknowledgements

We give thanks to the financial support of the National Natural Science Foundation of China (11076109), the Hong Kong Scholars Program (XJ2014045, G-YZ67), the "1000 Talents Plan" of the Sichuan Province, the Talent Introduction Program of Sichuan University (YJ201410), and the Innovation and Creative Experiment Program of Sichuan University (20171060, 20170133).

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Materials

List of materials used in this article
NameCompanyCatalog NumberComments
manganeseDaye Nonferrous Metals Group Holdings Co., Ltd.DJMnBproduced by electrolysis
copperDaye Nonferrous Metals Group Holdings Co., Ltd.Cu-CATH-2produced by electrolysis
NickelDaye Nonferrous Metals Group Holdings Co., Ltd.Ni99.99produced by electrolysis
IronNingbo Jiasheng Metal Materials Co., Ltd.YT01industrial pure Fe
ZincDaye Nonferrous Metals Group Holdings Co., Ltd.0#produced by electrolysis
AluminumDaye Nonferrous Metals Group Holdings Co., Ltd.Al99.90produced by electrolysis

References

  1. Zener, C. Elasticity and anelasticity of metals. , University of Chicago Press. (1948).
  2. Jensen, J. W., Walsh, D. F. Manganese-Copper damping alloys. Bulletin 624. , U.S. Department of the Interior, Bureau of Mines. Washington, DC. (1965).
  3. Wang, X. Y., Peng, W. Y., Zhang, J. H. Martensitic twins a....

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